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For a zero order reaction, the half-life...

For a zero order reaction, the half-life periof is independent of the initial concentration.

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For a first order reaction, the half-life period is independent of

Assertion (A): For a first order reaction, half-life period is independent of initial concentration of the reacting species.

Assertion : The decomposition of gaseous ammonia on a hot platinum surface is a zero order reaction at high pressure. For a zero order reaction the rate of reaction is independent of initial concentration.

Show that in first order reaction: i) Half-life period is independent of the initial molar concentration of the reaction. ii) Units of rate constant donot depend upon the units of concentration.

For a first order reaction, the half-life periof is 0.263 k .

Show that for the reactions of first order (i) Half-life period is independent of initial concentrations. (ii) Units of rate constant do not depend upon the units of concentration.

CENGAGE CHEMISTRY-CHEMICAL KINETICS-Exercises True/False
  1. The molecularity of a complex reaction is always greater than the orde...

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  2. For a zero order reaction, The rate becomes double when the order of t...

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  3. For a zero order reaction, the half-life periof is independent of the ...

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  4. x g of a radioactive substance will be decomposed to 7//8x g in 40 s i...

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  5. For a first order reaction, the half-life periof is 0.263 k.

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  6. The sum of powers to which of the concentration terms are raised in th...

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  7. The difference between the energy maximum along a reaction path and th...

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  8. The graph between log k versus 1//T is a straight line.

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  9. The slope of the tangent at a point on the curve of concentration of a...

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  10. A poistive catalyst increases the activation energy of the reaction.

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  11. The slope of straight line in a plot of log.[A] versus time for a firs...

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  12. The rate of reaction increases with increase in activation energy.

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  13. The average rate and instantaneous rate are the same.

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  14. Longer the reaction life time, faster is the reaction.

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  15. A mixture of reactants may be thermodynamically unstable but kinetical...

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  16. The rate constant of a specific reaction is independent of the concent...

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  17. The order of reaction can never be zero.

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  18. In a gaseous reaction, an increase in the pressure of the reactant gas...

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  19. The hydrolyiss of ethyl acetate in the pressure of sofium hydroxide is...

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  20. The unit of rate constant for a zero order reaction is s^(-1).

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