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Which of the following statements is/are...

Which of the following statements is/are correct?

A

A plot of `log k_(p)` versus `1//T` is linear.

B

A plot of `log[X]` versus time is linear for a first order reaction, `x rarr p`.

C

A plot of `log p` versus `1//T` is linear at constant volume.

D

A plot of `p` versus `1//V` is linear at constant temperature.

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

`ln k_(p) = lnA - (E_(a))/(R ) xx (1)/(T)(y = c+mx)`
Therefore, plotting a graph between `log K_(p)` versus `1//T` is a straight line.
For a first order reaction,
`log A_(t) = log A_(0)-(k)/(2.3)t(y = c+mx)`
The graph between `log A_(t)` and time is a straight line.
At constant temperature, `PV = ` constant for the given mass of a gas (Boyle's law). So, the graph between `P` and `1//V` is a straight line.
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