Home
Class 11
CHEMISTRY
Which of the following are diastereomers...

Which of the following are diastereomers ?

A

`(I) and (III)`

B

`(II) and (IV)`

C

`(I) and (II)`

D

None

Text Solution

Verified by Experts

The correct Answer is:
C

The Fischer projection of `(I) and (II)` is wrong because the functional group is not at the top. On rotating `(I) and (II)` by `180^(@)`. They are represented as shown:
(I)
Now, compare I,II,III, and IV

`(I) and (III)implies` Enantiomers
`(II) and (IV)implies` Identical or same
Therefore, the pairs of diastereomers are:
`(I), (II), (I), (IV)` , and `(II), (III)`
But the answer given is `(C ) (I, II)`.
Promotional Banner

Topper's Solved these Questions

  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning Type (Exercise)|5 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Fill in the blanks (Exercise)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Single correct answer type|13 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Archives Subjective|28 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos

Similar Questions

Explore conceptually related problems

Which of the following show diastereomers ?

Which of the following pairs are diastereomers?

Which one of the following is a diastereomer of (R )-4-bromo-cis-2-hexene?

R,S-configuration is a useful tool for determination of enantiomers, diasteromers and homomers. If configuration of all chiral centers are opposite then structures are enantiomers, if all chiral centers have same configuration then they are homomers and if some have same confguration and some have opposite configuration then they are diastereomers. Which of hte following is not diastereomer?

Which of the following compound give diastereomers when treated with Br_(2) in C Cl_(4) ?

CENGAGE CHEMISTRY-ISOMERISM-Single correct answer type (Exercise)
  1. Mesotartaric acid is optically inactive due to the presence of:

    Text Solution

    |

  2. Butene when treated with chlorine at about 500^(@)C forms:

    Text Solution

    |

  3. Which of the following are diastereomers ?

    Text Solution

    |

  4. An organic compound contains 66% C and 13.3% H. Its vapour density is ...

    Text Solution

    |

  5. Which of the following statements regarding the concept of resonance i...

    Text Solution

    |

  6. The keto form of phenol contains:

    Text Solution

    |

  7. Tautomerism is not exhibited by :

    Text Solution

    |

  8. The number of isomers of the compound C(2)FClBrl is :

    Text Solution

    |

  9. Pure enantiomeric acid+optically active alcohol having chiral C atom r...

    Text Solution

    |

  10. Racemic acid + optically active alcohol having chiral C atom rarr? T...

    Text Solution

    |

  11. PhCH(2)CH(Br)Phoverset(Alc.KOH)rarrProduct How many product are poss...

    Text Solution

    |

  12. Five compounds with formula C(4)H(8)Br(2) How many structrue of (X) ...

    Text Solution

    |

  13. Hydrogenation of the above compound in the presence of poisoned Pd cat...

    Text Solution

    |

  14. Hydrogenation of the compound by Brich reduction (Na+liq.NH(3)+C(2)H(...

    Text Solution

    |

  15. An SN^(2) reaction at an asymmetric C of a compound always gives:

    Text Solution

    |

  16. The nodal plane in the pi-bond of ethene is located in:

    Text Solution

    |

  17. Which of the following compounds exhibits stereoisomerism?

    Text Solution

    |

  18. Consider the following reaction: CH(3)-underset(D)underset(|)(CH)-un...

    Text Solution

    |

  19. Which of the following hydrocarbons has the lowest dipole moment?

    Text Solution

    |

  20. The geometrical isomerism is shown by:

    Text Solution

    |