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What kind of isomerism exists between [C...

What kind of isomerism exists between `[Cr(H_(2)O)_(6)]Cl_(3)` (violet) and `[Cr(H_(2)O)_(5)Cl].H_(2)O` (greyish-green)?

A

Linkage isomerism

B

Solvate isomerism

C

Ionisation isomerism

D

Coordination isomerism

Text Solution

Verified by Experts

The correct Answer is:
B
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Read the passage given below and answer the following questions : The existence of coordination compounds with the same formula but different arragements of the ligands was crucial in the development of coordination chemistry. Two or more compounds with the same formula but different arrangements of the atoms are called isomers. Isomers are compounds with the same molecular formula but different structural formulas and do not necessarily share similar properties. There are many different classes of isomers, like stereoisomers, enantiomers, and geometrical isomers. There are two main forms of isomerism: structural isomerism and stereoisomerism. The different chemical formulas in structural isomers are caused either by a difference in what ligands are bonded to the central atoms or how the individual ligands are bonded to the central atoms. The following questions are multiple choice questions. Choose the most appropriate answer: What kind of isomerism exists between [Cr(H_(2)O)_(6)] Cl_(3) (violet) and [Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O (greyishgreen) ?

What type of isomerism is shown by the pair [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O ?

The compounds [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(4) Cl_(2)]Cl.2H_(2)O represent