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Basic strength of CH-=overset(Theta)C(l)...

Basic strength of `CH-=overset(Theta)C(l), CH_(2)=overset(Theta) CH(II) and CH_(3)overset(Theta)CH_(2)(III)` will be in order

A

`I lt II lt III`

B

`II lt III lt I`

C

`III lt II lt I`

D

`III lt I lt =II`

Text Solution

Verified by Experts

The correct Answer is:
A

`underset(sp)underset(uarr)CH-=CH" " underset(sp^(2)) underset(uarr)(CH_(2))" " underset(sp^(3)) underset(uarr)(CH_(3))-CH_(3)`
Electronegative of carbon `sp gt sp^(2) gt sp^(3)`
Acidic `CH-= CH gt HC_(2) =CH_(2) gt CH_(3) -CH_(3)`
Basic `CH underset((II))-=C^(Theta) lt CH_(2) underset((II)) (-=)CH^(Theta) lt CH_(3)underset((III)) (-)CH_(2)^(Theta)`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-BASIC PRINCIPLES AND TECHNIQUES IN ORGANIC CHEMISTRY-EXERCISE 2
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  2. Which one of the following C-H bonds is the wekest for homolytic fissi...

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  3. In which of the following ways does the hydride ion tend to function ?

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  4. Most stable radical is

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  5. Select the incorrect statement .

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  6. Dehydrobromination (-HBr) of the following in increasing order is

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  7. The structural formula of 2-oxo-3-methyl-(N-bromo) butanamide is

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  8. Indicate the wrongly named compound

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  9. The most stable carbanion is

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  10. The most stable free radical among the following is

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  11. CH(3) overset(*) H(2) disproportionates to

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  12. Additionof HCI to 3,3 dimethyl but-1-ene yields two products, one of w...

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  13. Basic strength of CH-=overset(Theta)C(l), CH(2)=overset(Theta) CH(II) ...

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  14. Electrophile overset(o+)(NO(2)) attacks the following In which ca...

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  15. Major organic product fomred from the following sequence of reactions ...

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  16. Among the following, which is least acidic ?

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  17. In which of the following compounds, does the substituent not exert it...

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  18. When acidified sodium extract of organic compound is treated with acet...

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  19. The formation of yellow precipitate by the addition of solution of amm...

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  20. In Carius tube, the compound ClCH(2)COOH was heated with fuming HNO(3)...

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