Home
Class 12
CHEMISTRY
If the crystallises in zinc blende struc...

If the crystallises in zinc blende structure with `I^-` ions at lattice points. What fraction of tetrahedral voids is occupied by `Ag^+` ions ?

A

0.25

B

0.5

C

1

D

0.75

Text Solution

Verified by Experts

The correct Answer is:
B

In Agl crystals , number of `Ag^+` ions are equal to `I^-` ions . However , the number of tetrahedral voids are twice the number of atoms forming the cubic lattice .
`therefore` Number of tetrahedral voids occupied by `Ag^+` ions = 50%
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|12 Videos
  • SOLID STATE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise EXERCISE 1|77 Videos
  • S-BLOCK ELEMENTS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise Exercise 2|20 Videos
  • SOLUTIONS AND COLLIGATIVE PROPERTIES

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|25 Videos

Similar Questions

Explore conceptually related problems

In Zinc blende , the percentage of tetrahedral voids occupied by Zn^(2+) ions is :

AgI crystallises in a cubic close-packed ZnS structure. What fraction of tetrahedral sites is occupied by Ag^(+) ions ?

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-SOLID STATE-EXERCISE 2
  1. A crystal made of metal crystallises into a lattice containing a seque...

    Text Solution

    |

  2. In which of the following crystals, alternate tetrahedral voids are oc...

    Text Solution

    |

  3. If the crystallises in zinc blende structure with I^- ions at lattice ...

    Text Solution

    |

  4. The packing efficiency of the two dimensional square unit cell shown b...

    Text Solution

    |

  5. Silver (atomic weight 108 g mol^(-1)) has a density of 10.5 g cm^(-3)....

    Text Solution

    |

  6. In orthorhombic , the value of a, b and c are respectively 4.2Å, 8.6 Å...

    Text Solution

    |

  7. Consider the following statements I. NaCl and KCl show metal excess ...

    Text Solution

    |

  8. Consider the following statements I. Fe, Co, Ni CrO2 are ferrimagnet...

    Text Solution

    |

  9. CsBr crystallizes in a body centred cubic lattice,The unit cell length...

    Text Solution

    |

  10. If NaCl is doped with 10^(-4)mol%of SrCl(2) the concentration of cati...

    Text Solution

    |

  11. Which of the following statements is /are correc ? I. For a simple c...

    Text Solution

    |

  12. The ratio of packing fraction in fcc, bcc, and cubic structure is, res...

    Text Solution

    |

  13. How many Cs^+ ions occupy the second nearest neighbour location of a C...

    Text Solution

    |

  14. If R is the radius of the octahedral voids and r is the radius of the...

    Text Solution

    |

  15. What is the packing efficiency of a unit cell which is represented in...

    Text Solution

    |

  16. TiO(2) is well known example of :

    Text Solution

    |

  17. The edge length of a face centred cubic cell of an ionic substance is ...

    Text Solution

    |

  18. A solid has a bcc structure. If the distance of closest approach betwe...

    Text Solution

    |

  19. The ratio of closed packed atoms to tetrahedral holes in cubic close p...

    Text Solution

    |

  20. A binary silod(A^(+) B^(-)) has a zine blende stracture with B inos co...

    Text Solution

    |