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If two substances A and B have p(A)^(@):...

If two substances A and B have `p_(A)^(@): p_(B)^(@) = 1:2` and have mole fraction in solution as 1:2 then mole fraction of A in vapour phase is

A

0.33

B

0.25

C

0.52

D

0.2

Text Solution

Verified by Experts

The correct Answer is:
D

Mole fraction of component 'A' in vapour phase
`=(p_(A))/(p_(A)+p_(B))`
`"but "p_(A)=p_(A)^(@)x_(A)andp_(B)=p_(B)^(@)x_(B)=(p_(A)^(@)x_(A))/(p_(A)^(@)x_(A)+p_(B)^(@)x_(B))`
Mole fraction of component 'A' in vapour phase
`=(1xx1)/(1xx1+2xx2)=0.2`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-SOLUTIONS AND COLLIGATIVE PROPERTIES -Exercise 1 (Types of Solutions and Concentration of Solutions)
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  2. Which of the following liquid pairs shows a positive deviation from Ra...

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  3. If two substances A and B have p(A)^(@): p(B)^(@) = 1:2 and have mole ...

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  4. Relative lowering in vapour pressure of solution containing non-volati...

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  5. The vapour pressure of pure benzene at a certain temperature is 640 mm...

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  6. If M is molecular of solvent, K(b) is molal elevation constant, T(b) i...

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  7. Solute is non-volatile and solvent molecule is volatile. Which of the ...

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  8. When two liquids A and B are mixed, their boiling points become greate...

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  9. Vapour pressure of C CL(4) at 25^@C is 143 mmHg 0.05g of a non-volatil...

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  10. The vapour pressure of two liquids P and Q are 100 and 50 torr, respec...

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  11. Which of the following plot obeys the Raoult's law for all concentrati...

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  12. At 40^(@)C the vapour pressure of pure liquids, benzene and toluene, a...

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  13. The solution which shows large positive deviation from Raoult's law fo...

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  14. 1xx10^(3)m" solution of Pt "(NH(3))(4)Cl(4) " in "H(2)O shows depress...

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  15. What happens to freezing point of benzene when nephthalens is added ?

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  16. A 5.25% solution of a substance is isotonic with a 1.5% solution of ur...

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  17. The difference between the boiling point and freezing point of an aque...

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  18. A 6% of urea is isotonic with

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  19. Which of the following is not a colligative property?

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  20. In an osmotic pressure measurement experiment, a 5% solution of compou...

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