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20g of a binary electrolyte(mol.wt.=100)...

`20`g of a binary electrolyte(mol.wt.=`100`)are dissolved in `500`g of water.The freezing point of the solution is `-0.74^(@)CK_(f)=1.86K "molality"^(-1)`.the degree of ionization of the electrolyte is

A

`0%`

B

`100%`

C

`75%`

D

`50%`

Text Solution

Verified by Experts

The correct Answer is:
A

`DeltaT=(1000xxK_(f)xxw)/(mxx500)`
`0.74=(1000xx1.86xx20)/(mxx500)`
`mxx100`
`"Actual molecular mass"=100rArri=(100)/(100)=1+alpha`
`alpha=0`
`:.` The degree of ionisation of the electrolyte is 0%.
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