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The boiling point of 0.2 mol kg^(-1) sol...

The boiling point of `0.2 mol kg^(-1)` solution of `X` in water is greater than equimolal solution of `Y` in water. Which of the following statements is true in this case?

A

X is undergoing dissociation in water

B

Molecular mass of X is greater than the molecular mass of Y

C

Molecular mass of X is less than the molecular mass of Y

D

Y is undergoing dissociation in water while X undergoes no change

Text Solution

Verified by Experts

The correct Answer is:
A

`"Molality of solution X = molality of solution Y"`
`0.2mol//kg`
We know that, elevation in the boiling point `(DeltaT_(b))` of a solution is proportional to the molal concentration kof the solution `i.e.DeltaT_(b)proptomorDeltaT_(b)=K_(b)m`
where, m is the molality of the solution and `K_(b)` is molal boiling point constant or ebullioscopic constant.
`:.` Elevation in boiling point,
`DeltaT_(b)=iK_(b)morDeltaT_(b)proptoi`
where, i is van't Hoff's factor
Since, `DeltaT_(b)` of solution X is greater than `DeltaT_(b)` of solution Y. (Observed colligative property is greater than normal colligative property).
`:."i of solution X gt i of solution Y"`
`:.` Solution X undergoing dissociation.
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-SOLUTIONS AND COLLIGATIVE PROPERTIES -Exercise 2 (Miscellaneous Problems)
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  2. 1mol each of the following solutes are taken in 5mol water, (a)NaCl (...

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  3. The boiling point of 0.2 mol kg^(-1) solution of X in water is greater...

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  4. Density of 2.05 M solution of acetic acid in water is 1.02g//mL. The m...

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  5. In a 0.2 molal aqueous solution of a weak acid HX the degree of ioniza...

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  6. By dissolving 5 g substance in 50 g of water, the decrease in freezin...

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  7. The vapour pressure of pure liquid is 1.2 atm. When a non-volatile su...

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  8. How much C(2)H(5)OH must be added to 1.0"L of "H(2)O, so that solution...

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  9. On the basis of information given below mark the correct option. Inf...

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  10. If sodium sulphate is considered to be completely dissociated into cat...

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  11. The vapour pressure of water at 20^(@) is 17.5 mmHg. If 18 g of glucos...

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  12. An aqueous solution of 2 per cent (wt.//wt) non-volatile solute exerts...

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  13. On mixing, heptane and octane form an ideal solution. At 373K the vapo...

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  14. To neutralize completely 20 mL of 0.1M aqueous solution of phosphorus ...

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  15. The degree of dissociation (alpha) of a weak electrolyte A(x)B(y) is ...

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  16. A solution of Al(2)(So(4))(3){d=1.253 gm//ml} contain 22% salt by weig...

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  17. A solution is obtained by mixing 300 g of 25% solution and 400 g of 40...

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  18. Which of the following aqueous solutions produce the same osmotic pres...

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  19. 138 g of ethyl alcohol is mixed with 72 g of water. The ratio of mole ...

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  20. The vapour pressure lowering caused by addition of 100 g of sucrose (m...

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