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A solution of 1.25of 'P' in 50g of water...

A solution of `1.25of 'P'` in 50g of water lawers freezing point by `0.3^(@)C` . Molar mass of 'P' is `94.K_(f("water"))=1.86"K kg mol"^(-1)*` The degree of association of 'P' in water is

A

0.8

B

0.6

C

0.65

D

0.75

Text Solution

Verified by Experts

The correct Answer is:
A

`DeltaT_(f)=ixxK_(f)xxm`
`0.3=ixx1.86xx(1.25xx1000)/(50xx94)=0.6064`
`" Degree of association, " alpha=(i-1)/(1/n-1)=(0.6064-1)/(1/2-1)`
`=78.72%~~80%`
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