Home
Class 12
CHEMISTRY
The coordination number and the oxidatio...

The coordination number and the oxidation state of the element 'E' in the complex `[E(en)_2(C_2O_4)]NO_2` (where `(en)` is ethylenediamine) are, respectively

A

6 and 2

B

4 and 3

C

4 and 3

D

6 and 3

Text Solution

Verified by Experts

The correct Answer is:
D

`en {:(CH_(2) -NH_(2)),(|),(CH_(2)-NH_(2)):}` is a bidetate ligand
is a bidentate ligand .
Hence , coordinating sites for ` [E(en)_(2))C_(2)O_(4))]^(+)NO_(2)^(-)`
Let , x be the charge on the E
` x+2(0) +(-2) =+1`
` x=+3`
` therefore ` Oxidation number is 3.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|7 Videos
  • COORDINATION COMPOUNDS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise Exercise 1|85 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|11 Videos
  • D - AND F-BLOCK ELEMENTS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|27 Videos

Similar Questions

Explore conceptually related problems

The sum of coordination number and oxidation number of the metal M in the complex [M(en)_2(C_2O_4)]Cl (where en is ethylenediamine) is:

The sum of coordination number and oxidation number of the metal M in the complex [M(en)_(2) (C_(2)O_(4))]CI (where en is ethylenediamine) is:

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-COORDINATION COMPOUNDS-Exercise2 (Miscellaneous Problems)
  1. Which has maximum paramagnetic character ?

    Text Solution

    |

  2. Which of the following does not have a metal carbon bond?

    Text Solution

    |

  3. The coordination number and the oxidation state of the element 'E' in ...

    Text Solution

    |

  4. The metal ion in complex underline(A ) has EAN identical to t...

    Text Solution

    |

  5. [CoCl(2) (NH(3))(4)]^(+)Cl^(-) ( green )and [CoCl(2)(NH(3))(4) ]^...

    Text Solution

    |

  6. Classify the following structures into nitro -N A nitrito -O-B t...

    Text Solution

    |

  7. Which isomerism is repeseted by the following square planar com...

    Text Solution

    |

  8. InK contains Fe^(3+) .Spot of ink can be removed by addition of ...

    Text Solution

    |

  9. Hexaammineplatinum (IV ) tetracloridoplatinate (II ) is

    Text Solution

    |

  10. Which of the following will give a pair of enantiomorphs? .

    Text Solution

    |

  11. Coordination number of Cr is three. A comlex ion of Cr with C(2)O(4)^(...

    Text Solution

    |

  12. The stabilization of coordination compound due to chelation is called ...

    Text Solution

    |

  13. The colour of the coordination compounds depends on the crystal field ...

    Text Solution

    |

  14. Which of the following is obtained when auric chloride reacts ...

    Text Solution

    |

  15. Consider the following complexes: (I) K(2)Ptcl(6) (II) PtCl(4).2...

    Text Solution

    |

  16. EAN of cobalt is 36 in [Co(NH(3))(2) O(2)(en)Cl] thus ,O(2) ...

    Text Solution

    |

  17. A correct statement is

    Text Solution

    |

  18. Which among the following will be named as dibromidobis ( ethye...

    Text Solution

    |

  19. Which of the following is a negatively charged bidentable ligan...

    Text Solution

    |

  20. Consider the follwing complexes ion P,Q and R P =[FeF(6)]^(3-), Q=[V...

    Text Solution

    |