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Which of the following reactions is/are ...

Which of the following reactions is/are feasible?

A

`CH_(3)CH_(2)Br+overset(+)NaO^(-)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3) rarr CH_(3)CH_(2)O-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3)`

B

`CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-Cl+Na^(+)O^(-)CH_(2)CH_(3)rarrCH_(3)CH_(2)-O-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3)`

C

Both a and b

D

None of the above

Text Solution

AI Generated Solution

The correct Answer is:
To determine the feasibility of the given reactions, we need to analyze each reaction based on the SN2 mechanism and the concept of steric hindrance. ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction involves CH3CH2Br (ethyl bromide) reacting with NaO-C(CH3)3 (tert-butoxide). - The second reaction involves a tertiary alkyl halide. 2. **Understand the SN2 Mechanism**: - In an SN2 reaction, a nucleophile attacks an electrophile (alkyl halide), leading to the displacement of a leaving group (halide ion). - The reaction proceeds in a single step, and the rate depends on the concentration of both the nucleophile and the substrate. 3. **Evaluate Steric Hindrance**: - **First Reaction**: - The alkyl halide (ethyl bromide) is a primary halide, which means it has minimal steric hindrance. - The nucleophile (tert-butoxide) can easily approach and attack the carbon atom, leading to the formation of the ether product. - Therefore, this reaction is feasible. - **Second Reaction**: - The alkyl halide is tertiary, meaning it has three alkyl groups attached to the carbon atom. - The steric hindrance is significant, making it difficult for the nucleophile to attack the carbon atom. - Instead of an SN2 reaction, an elimination reaction occurs, leading to the formation of an alkene as the major product. - Hence, this reaction is not feasible for the formation of an ether. 4. **Conclusion**: - The first reaction is feasible, while the second reaction is not feasible for ether formation. ### Final Answer: - The correct answer is that only the first reaction (Option A) is feasible.

To determine the feasibility of the given reactions, we need to analyze each reaction based on the SN2 mechanism and the concept of steric hindrance. ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction involves CH3CH2Br (ethyl bromide) reacting with NaO-C(CH3)3 (tert-butoxide). - The second reaction involves a tertiary alkyl halide. ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-MHT CET Corner
  1. Which of the following reactions is/are feasible?

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  2. Isopropyl methyl ether when treated with cold hydrogen iodide gives

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  3. Which among the following phenolic compounds is most acidic in nature?

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  4. Name the catalyst used in commerical method of preparation of phenol.

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  5. Which of the following compounds has highest boiling point ?

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  6. Reaction of which among the following ethers with Hl in cold leads to ...

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  7. Select of the ether among following that yields methanol as one of the...

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  8. The order of stability of the following tautomeric compound is I. C...

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  9. The nature of 2,4,6-trinitro phenol is

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  10. Which of the following organic compounds could not be dried by anhydro...

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  11. Which of the following dissolves in ionic solvents?

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  12. Phenol gives characteristic colouration with

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  13. 1 mole alcohol reacts with Na to give what weight of hydrogen?

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  14. The relative ease of dehydration of alcohols follows following order :

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  15. Ethanolic KOH gives

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  16. Which of the following compounds is optically active ?

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  17. Which alcohol of molecular formula C(4)H(9)OH cannot be obtained by th...

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  18. Ether and alcohol are …………. Isomers.

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  19. The IUPAC name of {:(H(3)C-CH-C(3)H(7)),(" |"),(" "...

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  20. Phenols are more acidic than alcohols because

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  21. is the anhydride of

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