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Salicylaldehyde is obtained when phenol ...

Salicylaldehyde is obtained when phenol is heated with `CHCl_(3)` and aqueous NaOH. This reaction is known by which name?

A

Carbylamine reaction

B

Hofmann's reaction

C

Reimer-Tiemann reaction

D

Kolbe-Schmidt reaction

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The correct Answer is:
To determine the name of the reaction in which salicylaldehyde is obtained when phenol is heated with chloroform (CHCl₃) and aqueous sodium hydroxide (NaOH), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol, chloroform (CHCl₃), and aqueous sodium hydroxide (NaOH). 2. **Understand the Reaction Conditions**: - The reaction involves heating phenol with CHCl₃ in the presence of NaOH. This indicates that a chemical transformation is occurring under basic conditions. 3. **Recognize the Product**: - The product of this reaction is salicylaldehyde, which is an aromatic aldehyde. 4. **Recall the Mechanism**: - In this reaction, phenol reacts with chloroform in the presence of a strong base (NaOH) to form a dichlorocarbenium ion, which acts as an electrophile. This electrophile then attacks the phenol to produce salicylaldehyde. 5. **Name the Reaction**: - This specific reaction is known as the **Riemert reaction**. More specifically, it is referred to as **Riemert formylation** when it involves the formation of an aldehyde like salicylaldehyde. ### Final Answer: The reaction is known as the **Riemert reaction** or **Riemert formylation**.

To determine the name of the reaction in which salicylaldehyde is obtained when phenol is heated with chloroform (CHCl₃) and aqueous sodium hydroxide (NaOH), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol, chloroform (CHCl₃), and aqueous sodium hydroxide (NaOH). 2. **Understand the Reaction Conditions**: ...
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