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Phenol is heated with a solution of mixt...

Phenol is heated with a solution of mixture of `KBr` and `KBrO_(3)`. The major product obtained in the above reaction is

A

2-bromophenol

B

3-bromophenol

C

4-bromophenol

D

2, 4, 6-tribromophenol

Text Solution

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The correct Answer is:
D

`Br_(2)` is formed by a redox reaction
`5Br^(-)+BrO_(3)^(-) +6H^(+)rarr 3Br_(2)+3H_(2)O`
`-OH` group is the activating group and there is `S_(E)` at o-and p-positions giving yellowish white precipitate of 2, 4, 6-tribromophenol
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