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For the sequence of reactions, Aoverse...

For the sequence of reactions,
`Aoverset(C_(2)H_(5)Mgl)rarr B overset(H_(2)O //H^(+))rarr "tert- pentyl alcohol."`
The compound A will be

A

2-butanone

B

acetaldehyde

C

acetone

D

propanal

Text Solution

Verified by Experts

The correct Answer is:
C

`underset("Acetone")underset("'A'")(H_(3)C-underset(CH_(3))underset("| ")"C "=O)overset(C_(2)H_(5)Mgl)underset("Ether")rarrH_(3)C-CH_(2)-overset(overset(-)Ooverset(+)Mgl)overset("| ")underset("'B'")underset(CH_(3))underset("| ")"C "-CH_(3)overset(H_(2)O //H^(+)) underset(-Mg(OH)I)rarrunderset(" Tert - pentyl alcohol")(H_(3)C-CH_(2)-overset(OH)overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3))`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 2 (MISCELLANEOUS PROBLEMS))
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  2. 0.44 g of a monhydric alcohol when added to methyl magnesium iodide in...

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  3. For the sequence of reactions, Aoverset(C(2)H(5)Mgl)rarr B overset(H...

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  4. R-CH(2)-CH(2)OH can be converted into RCH(2)CH(2)COOH the correct seq...

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  6. An unknown alcohol is treated with the ''Lucas reagent'' to determine ...

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  7. Ethyl cloride reacts with sodium ethoxide to form a compound (A)Which ...

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  8. Identify A and B

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  9. The cleavage of an aryl-alkyl ether with cold HI gives

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  10. The major product A is

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  11. Which of the following alcohols is unable to turn orange colour of chr...

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  12. Hydroboration oxidation of 4-methyl octene would give

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  13. Acid catalysed hydration of alkenes except ethene leads to the formati...

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  14. The function of ZnCl(2) in Lucas test for alcohols is

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  15. Which one of the following is most acidic ?

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  16. Consider the following reaction, C(2)H(5)OH+H(2)SO(4)rarr Product ...

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  17. Compound Ph-O-overset(O)overset(||)(C)-Ph can be prepared by the react...

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  18. Which one of the following compounds will not react with CH(3)MgBr?

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  19. R-CH(2)-CH(2)OH can be converted into RCH(2)CH(2)COOH the correct seq...

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  20. Among the following compounds which can be dehydrated very easily is-

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