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Which one of the following compounds wil...

Which one of the following compounds will not react with `CH_(3)MgBr`?

A

Ethyl acetate

B

Acetone

C

Dimethyl ether

D

Ethanal

Text Solution

Verified by Experts

The correct Answer is:
C
Grignard reagent (RMgX) reacts with only those compounds which contains acidic hydrogen or which contains carbonyl group. Dimethyl ether `(CH_(3)OCH_(3))` due to absence of both acidic hydrogen and carbonyl group does not react with Grignard reagent.
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 2 (MISCELLANEOUS PROBLEMS))
  1. Consider the following reaction, C(2)H(5)OH+H(2)SO(4)rarr Product ...

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  2. Compound Ph-O-overset(O)overset(||)(C)-Ph can be prepared by the react...

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  3. Which one of the following compounds will not react with CH(3)MgBr?

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  4. R-CH(2)-CH(2)OH can be converted into RCH(2)CH(2)COOH the correct seq...

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  5. Among the following compounds which can be dehydrated very easily is-

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  6. In the following reaction which bonds are cleaved? CH(3)CH(2)-overse...

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  7. Consider the following reaction,

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  9. The best method to prepare cyclohexene from cyclohexanol is by using

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  10. In the above dehydration reaction .^(18)C will be in

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  11. underset(OH)underset(|)(CH(2)=CHCHCH(2)CH(2)OH)overset(MnO(2))rarrA,A ...

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  12. Two aromatic compounds having formula C(7)H(8) O which are easily iden...

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  13. Select the schemes A, B C out of I. acid catalysed hydration II. H...

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  14. The major product obtained on interaction of phenol with sodium hydrox...

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  15. Ester A(C(4)H(8)O(2))+underset("(2 parts)")(CH(3)MgBr)overset(H(3)O^(+...

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  16. Which of the following compound would not evolve CO(2) when treated wi...

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  17. CH(3)-overset(CH(3))overset("| ")underset(CH(3))underset("| ")"C "-u...

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  18. Phenol is heated with C Cl(4) and alkaline KOH when salicylic acid is ...

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  19. Which of the following would yield a secondary alcohol after the indic...

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  20. Phenol on reaction with CHCl(3) and NaOH give salicylaldehyde. Interme...

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