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Which one of the following reaction woul...

Which one of the following reaction would produce secondary alcohol?

A

`C_(6)H_(6)overset(O)overset(||)"C"CH_(3) overset(CH_(3)Mg Br, H^(+))rarr `

B

`C_(6)H_(5)overset(O)overset(||)C CH_(3) overset(LiAlH_(4)H^(+))rarr`

C

`CH_(3)CHO overset(LiAlH_(4),H^(+))rarr`

D

`CH_(3)overset(O)overset(||)C CH_(3) overset(OH^(Theta),Br_(2))rarr`

Text Solution

Verified by Experts

The correct Answer is:
B
`underset("Acetophenone")(C_(6)H_(5)-overset(O)overset(||)C-CH_(3))overset((i)LiAlH_(4))underset((ii)H^(+))rarr underset("alcohol")underset("Secondary")(C_(6)H_(5)-overset(OH)overset("| ")"CH"-CH_(3))`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 2 (MISCELLANEOUS PROBLEMS))
  1. R-CH(2)-CH(2)OH can be converted into RCH(2)CH(2)COOH the correct seq...

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  2. Among the following compounds which can be dehydrated very easily is-

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  3. In the following reaction which bonds are cleaved? CH(3)CH(2)-overse...

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  4. Consider the following reaction,

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  6. The best method to prepare cyclohexene from cyclohexanol is by using

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  7. In the above dehydration reaction .^(18)C will be in

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  8. underset(OH)underset(|)(CH(2)=CHCHCH(2)CH(2)OH)overset(MnO(2))rarrA,A ...

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  9. Two aromatic compounds having formula C(7)H(8) O which are easily iden...

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  10. Select the schemes A, B C out of I. acid catalysed hydration II. H...

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  11. The major product obtained on interaction of phenol with sodium hydrox...

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  12. Ester A(C(4)H(8)O(2))+underset("(2 parts)")(CH(3)MgBr)overset(H(3)O^(+...

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  13. Which of the following compound would not evolve CO(2) when treated wi...

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  14. CH(3)-overset(CH(3))overset("| ")underset(CH(3))underset("| ")"C "-u...

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  15. Phenol is heated with C Cl(4) and alkaline KOH when salicylic acid is ...

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  16. Which of the following would yield a secondary alcohol after the indic...

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  17. Phenol on reaction with CHCl(3) and NaOH give salicylaldehyde. Interme...

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  18. In the presence of dry HCl gas, CH(3)CHO condenses with C(2)H(5)OH to ...

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  19. In the reaction , The products are

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  20. Which one of the following reaction would produce secondary alcohol?

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