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How is nitrogen prepared in the laborato...

How is nitrogen prepared in the laboratory ?
Write the chemical equations of the reactions involved.

Text Solution

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Preparation of di Nitrogen :
`to` Very pure nitrogen is obtained by the thermal decomposition of sodium (or) barium a-zide.
`"Ba"(N_(3))_(2)to"Ba"+3N_(2)`
`to` In the laboratory dinitrogen is prepared by treating an aqueous solution of `"NH"_(4)Cl` with `"NaNO"_(2)`
`"NH"_(4)Cl_(("aq"))+"NaNO"_(2("aq"))toN_(2_((g)))+2H_(2)O_((1))+"NaCl"_(("aq"))`
`to` Nitrogen can also be obtained by the thermal decomposition of ammonium dichromate.
`(NH_(4))_(3)"Cr"_(2)O_(7)overset(Delta)toN_(2)+4H_(2)O+"Cr"_(2)O_(3)`
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-P-BLOCK ELEMENTS -GROUP 15 ELEMENTS (VERY SHORT ANSWER QUESTIONS)
  1. Why does the reactivity of nitrogen differ from phosphorus ?

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  2. How is nitrogen prepared in the laboratory ? Write the chemical equa...

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  3. Nitrogen exists as diatomic molecule and phosphorus as P(4) - Why ?

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  4. Why does nitroggen show catenation properties less than phosphorus ?

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  5. Nitrogen molecule is highly stable - Why ?

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  6. Why are the compounds of bismuth more stable in +3 oxidation state ?

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  7. What is allotropy ? Explain the different allotropic forms of phosphou...

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  8. How do you account for the inert character of dinitrogen ?

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  9. Explain the difference in the structures of white and red phosphorus.

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  10. How is alpha- black phosphorus prepared from red phosphorus ?

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  11. Write the difference between the properties of white phosphorus and re...

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  12. What is inert pair effect ?

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  13. Explain why is NH(3) basic while "BiH"(3) is only feebly basic.

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  14. Arrange the hydrides of group - 15 elements in the increasing order of...

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  15. PH(3) is a weaker base than NH(3) - Explain.

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  16. A hydride of group -15 elements dissolves in water to form a bbasic so...

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  17. What happens when white phosphorus is heated with conc. NaOH solution ...

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  18. NH(3) forms hydrogen bonds but PH(3) does not - why ?

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  19. The HNH angle is higher than HPH, HAsH and HSbH angles - Why ?

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  20. How do calcium phosphide and heavy water react ?

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