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Nitrogen exists as diatomic molecule and...

Nitrogen exists as diatomic molecule and phosphorus as `P_(4)` - Why ?

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Nitrogen exists as diatomic molecule :
`to` Nitrogen has small size and high electronegativity and nitrogen atom forms `P pi-P pi` multiple bonds with it self (triple bond). So it exists as a discrete diatomic molecule in elementary state.
Phosphorus exists as tetra atomic molecule :
`to` Phosphorus has large size and less electronegative and it forms P-P single bonds. So it exists as tetra atomic i.e., `P_(4)`.
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The following can exist as a diatomic molecule

Nitrogen forms a simple diatomic molecule but other elements of same group do not form. Explain.

Mention the shortest and longest diatomic molecules.

(A) Nitrogen is a gas, where as phosphorus is a solid (R ) Nitrogen can form (P-P) pi bonds in effective manner when compared to phosphorus

Why does hydrogen occur as a diatomic molecule under normal conditions ?

(A) From Nitrogen to phosphorus increase in atomic radii is more when compared to increase in size from P to As (R ) Nitrogen is a gas at room temperature where as P_(4) is a solid at room temperature

Nitrogen (atomic number 7) and phosphorus (atomic number 15) belong to group 15 of the Periodic Table. Write the electronic configuration of these two elements. Which of these will be more electronegative ? Why ?

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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-P-BLOCK ELEMENTS -GROUP 15 ELEMENTS (VERY SHORT ANSWER QUESTIONS)
  1. Why does the reactivity of nitrogen differ from phosphorus ?

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  2. How is nitrogen prepared in the laboratory ? Write the chemical equa...

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  3. Nitrogen exists as diatomic molecule and phosphorus as P(4) - Why ?

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  4. Why does nitroggen show catenation properties less than phosphorus ?

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  5. Nitrogen molecule is highly stable - Why ?

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  6. Why are the compounds of bismuth more stable in +3 oxidation state ?

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  7. What is allotropy ? Explain the different allotropic forms of phosphou...

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  8. How do you account for the inert character of dinitrogen ?

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  9. Explain the difference in the structures of white and red phosphorus.

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  10. How is alpha- black phosphorus prepared from red phosphorus ?

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  11. Write the difference between the properties of white phosphorus and re...

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  12. What is inert pair effect ?

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  13. Explain why is NH(3) basic while "BiH"(3) is only feebly basic.

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  14. Arrange the hydrides of group - 15 elements in the increasing order of...

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  15. PH(3) is a weaker base than NH(3) - Explain.

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  16. A hydride of group -15 elements dissolves in water to form a bbasic so...

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  17. What happens when white phosphorus is heated with conc. NaOH solution ...

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  18. NH(3) forms hydrogen bonds but PH(3) does not - why ?

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  19. The HNH angle is higher than HPH, HAsH and HSbH angles - Why ?

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  20. How do calcium phosphide and heavy water react ?

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