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Starting from elemental sulphur, how is ...

Starting from elemental sulphur, how is `H_(2)SO_(4)` prepared ?

Text Solution

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Manufacture of `H_(2)SO_(4)` by contact process :
Manufacturing of `H_(2)SO_(4)` involves three main steps,
Step - I
`SO_(2)` production : The required `SO_(2)` for this process is obtained by burning S(or) Iron pyrites in oxygen.
`S+O_(2)toSO_(2)`
`4FeS_(2)+15O_(2)to2Fe_(2)O_(3)to2Fe_(2)O_(3)+8SO_(3)`
Step - 2
`SO_(3)` formation : `SO_(2)` is oxidised in presence of catalyst with atmospheric airto form `SO_(3)`
`2SO_(2(g))+O_(2(g))underset(Delta)overset("catalyst")iff2SO_(3(g))`
Step - 3
Formation of `H_(2)SO_(4)` : `SO_(3)` formed in the above step absorbed in `98% H_(2)SO_(4)` to get oleum `(H_(2)S_(2)O_(7))`. This oleum is diuted to get desired concentration of `H_(2)SO_(4)`.
`SO_(3)+H_(2)SO_(4)toH_(2)S_(2)O_(7)`
`H_(2)S_(2)O_(7)+H_(2)Oto 2H_(2)SO_(4)`
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-P-BLOCK ELEMENTS -GROUP 16 ELEMENTS (SHORT ANSWER QUESTIONS)
  1. Describe the manufacture of H(2)SO(4) by contact process.

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  2. How is ozone prepared ? How does it react with the following ? PbS

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  3. How is ozone prepared ? How does it react with the following ? KI

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  4. How is ozone prepared ? How does it react with the following ? Hg

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  5. How is ozone prepared ? How does it react with the following ? Ag

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  6. Write a short note on the allotropy of sulphur.

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  7. How does SO(2) react with the following ? Na(2)SO(3)("aq")

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  8. How does SO(2) react with the following ? Cl(2)

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  9. How does SO(2) react with the following ? "Fe"^(+3)"ions"

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  10. How does SO(2) react with the following ? "KMnO"(4)

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  11. Starting from elemental sulphur, how is H(2)SO(4) prepared ?

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  12. Describe the structures (shapes) of SO(4)^(-2) and SO(3).

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  13. Which oxide of sulphur can act as both oxidizing and reducing agent ?...

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  14. Explain the conditions favourable for the formation of SO(3) from SO(2...

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  15. Complete the following KCl+H(2)SO(4)to

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  16. Complete the following "Sucrose"overset("Conc.H"(2)SO(4))to

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  17. Complete the following Cu+H(2)SO(4)("Conc")to

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  18. Complete the following C+H(2)SO(4)("Conc")to

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  19. Which is used for drying ammonia ?

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  20. Why conc "H"(2)"SO"(4),"P"(4)"O"(10) and anhydrous CaCl(2) cannot be u...

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