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How is O(3) estimated quantitatively ?...

How is `O_(3)` estimated quantitatively ?

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When ozone reacts with an excess of potassium iodide solution buffered with a borate buffer (pH 9.2), iodine is liberated which can be titrated against a standard solution of sodium thiosulphate. In this way `O_(3)` can be estimated quantitatively.
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There are two types of iodine titrations (a) Iodometric & (b) Iodimetric, Iodometric method is indirect method of I_(2) estimation. Any oxidant which liberates I_(2) from KI solution, the liberated iodine is estimated by titrating it with Na_(2)S_(2)O_(3) solution as : I_(2)+2Na_(2)S_(2)O_(3)rarr2NaI+Na_(2)S_(4)O_(6) 100 mL of .x. M K_(2)Cr_(2)O_(7) solution is added to excess of KI solution in acidic medium. The liberated iodine required 50 mL of 0.1N Na_(2)S_(2)O_(3) solution. The value of x is

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