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Why is it difficult to obtain M^(3+) oxi...

Why is it difficult to obtain `M^(3+)` oxidation state in Ni, Cu and Zn ?

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`rarr` Ni has electronic configuration `[Ar]4s^(2)3d^(8)`
`Ni^(+2)` has electronic configuration `[Ar]4s^(0)3d^(8)`
It is difficult to remove an electron from `3d^(8).` So, `Ni^(+3)` is difficult to obtain. (Ni has high negative enthalpy of hydration).
`rarr` Cu has electronic configuration `[Ar]4s^(1)3d^(10)`
`Cu^(+)` has electronic configuration `[Ar]3d^(10)`
It is difficult to remove the electrons from `3d^(10)` (stable). So, `Cu^(+3)` is difficult to obtain.
`rarr` Zn has electronic configuration `[Ar]4s^(2)3d^(10)`
`Zn^(+2)` has electronic configuration `[Ar]4s^(0)3d^(10)`
It is difficult to remove the electron from `3d^(10)` (stable). So `Zn^(+3)` is difficult to obtain.
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-D AND F- BLOCK ELEMENTS AND CO-ORDINATION COMPOUNDS -VERY SHORT ANSWER QUESTIONS
  1. Why do transition elements exhibit more than one oxidation state (varl...

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  2. Though Sc is a transition element, it does not exhibit variable oxidat...

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  3. Why is it difficult to obtain M^(3+) oxidation state in Ni, Cu and Zn ...

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  4. Why is Cr^(2+) reducing and Mn^(3+) oxidizing even though both have th...

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  5. Although Cr, Mo and W belong to the same group (group 6) Cr (VI) is a ...

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  6. What do you infer from the fact that M^(3+)//M^(2+) standard electrode...

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  7. Transition elements have high melting points. Why ?

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  8. Among the first transition series (3d series) Chromium has highest mel...

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  9. Compared to s-block elements, the transition elements exhibit higher e...

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  10. Among the first transition series (3d series) zinc has lowest enthalpy...

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  11. How do rou expect the density of transition elements to vary in a give...

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  12. How do the atomic and ionic sizes vary among transition metals in a gi...

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  13. Why do Mn, Ni and Zn exhibit more negative E^(Theta) values than expec...

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  14. Among the first transition series (3d series) only copper has positive...

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  15. Cu^(+2) forms halides like CuF(2), CuCl(2) and CuBr(2) but not CuI(2)....

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  16. The highest Mn fluoride is MnF(4) where as the highest oxide is Mn(2)O...

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  17. In its fluoride or Oxide, in which a transition metal exhibits highest...

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  18. Why Zn^(2+) is diamagnetic whereas Mn^(2+) is paramagnetic ?

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  19. Write 'spin only' formula to calculate the magnetic moment of transiti...

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  20. Calculate the 'spin only' magnetic moment of Fe(aq)^(2+) ion.

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