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Explain the terms Ligand...

Explain the terms
Ligand

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Ligand : The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be
a) simple ions such as `Cl^(-)`
b) small molecules such as `H_(2)O" or "NH_(3)`
c) large molecules such as `H_(2)NCH_(2)CH_(2)NH_(2)" or "N(CH_(2)CH_(2)NH_(2))_(3)` or even (d) macro-molecules, such as proteins.
On the basis of the number of donor atoms available for coordination, the ligands can be classified as :
a) Unidentate : One donor atom, `Eg. : overset(..)NH_(3), :overset(..)underset(..)Cl:` etc.
b) Bidentate : Two donor atoms, `Eg. : H_(2)NCH_(2)CH_(2)NH_(2)`
(ethane-1,2-diamine or en), `C_(2)O_(4)^(2-)` (oxalate), etc.
c) Polydentate : More than two donor atoms Eg. `:N(CH_(2)CH_(2)NH_(2))_(3))` EDTA. etc.
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-D AND F- BLOCK ELEMENTS AND CO-ORDINATION COMPOUNDS -SHORT ANSWER QUESTIONS
  1. Give the geometrical shapes of the following complex entities [PtCl(...

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  2. Give the geometrical shapes of the following complex entities [Fe(CN...

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  3. Explain the terms Ligand

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  4. Explain the terms Coordination number

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  5. Explain the terms Coordination entity

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  6. Explain the terms Central metal atom/ion.

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  7. Explain the terms Unidentate ligand

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  8. Explain the terms bidentate ligand

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  9. Explain the terms polydentate ligand

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  10. Explain the terms ambidentate ligand giving one example for each.

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  11. What is meant by chelate effect ? Give example.

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  12. Give the oxidation numbers of the central metal atoms in the following...

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  13. Give the oxidation numbers of the central metal atoms in the following...

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  14. Give the oxidation numbers of the central metal atoms in the following...

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  15. Give the oxidation numbers of the central metal atoms in the following...

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  16. Using IUPAC norms write the formulas for the Tetrahydroxozincate (II)

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  17. Using IUPAC norms write the formulas for the Hexaamminecobalt (III) su...

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  18. Using IUPAC norms write the formulas for the Potassium tetrachloropall...

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  19. Using IUPAC norms write the formulas for the Potassium tri(oxalato) ch...

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  20. Using IUPAC norms write the systematic names of the [Co(NH(3))(6)]Cl(3...

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