Sketch the splitting of d orbitals in an...

Sketch the splitting of d orbitals in an octahedral crystal field,

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In octahedral complexes having co-ordination number 6, the degeneracy of the d-orbitals of central atom is removed due to ligand electron metal electron repulsions. In the octahedral complex three orbitals have lower energy, t_(2g) set and two orbitals have higher energy, eg set. This phenomenon is formed as crystal field splitting and the energy seperation is denoted by Delta_(0) . Thus the energy of the two eg orbitals will increase by (3//5)Delta_(0) and that of the three t_(2g) will decrease by (2//5)Delta_(0) . The erystal field splitling, Delta_(0) depends upon the field produced by the ligand and charge on the metal ion. Some ligands are able to produce strong field and in these cases, the splitting will be large whereas other produce weak fields and consequently result in small splitting of d-orbitals. In an octahedral crystal field, t_(2g) orbitals are

According to CFT the energy of t_(2g) orbitals in an octahedral complex

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Sketch the shape of s and p-orbital indicating the angular distribution of electrons

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Low spin complex of d^6 - cation in an octahedral field willhave the following energy. ( Delta_0 = crystal field splitting energy in an octahedral field, P= Electron pairing energy)

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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-D AND F- BLOCK ELEMENTS AND CO-ORDINATION COMPOUNDS -LONG ANSWER QUESTIONS

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