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Give one chemical test of distinguish be...

Give one chemical test of distinguish between the following pairs of compounds.
Aniline and N.Methylaniline

Text Solution

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Aniline `(1^(@) - "amine")` and N.Methyl `(2^(@) - "amine")` aniline are distinguished by carbylamine test (or) isocyanide test. Aniline responds to carbyl amine test to give foul smelling phenyl iso cyanide where as N - methyl aniline does not responds to carbyl amine Test.
`C_(6)H_(5)NH_(2)+CHCl_(3)+ak.KOH overset(Delta)to underset("(Foul smelline)") underset("Phenyl isocyamide")(C_(6)H_(5)NC+3KCl+3H_(2)O)`
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Knowledge Check

  • One among the following pairs of compounds are not isomers?

    A
    `(CH_(3))_(2)CH- O-C_(2)H_(5) and CH_(3) (CH_(2))_(2) - O-C_(2)H_(5)`
    B
    `CH_(3)CH_(2)CO_(2)H and CH_(3)CO_(2)CH_(3)`
    C
    `CH_(3)COCH_(3) and CH_(3)CH_(2)CH_(2)OH`
    D
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  • The IUPAC names of the following pair of compounds are

    A
    Cis-2-butene and trans-2-butene
    B
    2-Butene and methylpropene
    C
    Trans -2-butene and cis-2-butene
    D
    Methylpropene and methylpropene
  • Identify the correct reagent(s) to distinguish between pairs of compounds given

    A
    proponal & propanone can be distinguished by using `I_2 & NaOH`
    B
    Benzaldehyde and acetophenone `(C_6 H_5 COCH_3)` can be distinguished with Tollen's reagent
    C
    D
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