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The average translational energy and the rms speed of molecules in a sample of oxygen gas at `300K` are `6.21xx10^(-21)J` and `484m//s`, respectively. The corresponding values at `600K` are nearly (assuming ideal gas behaviour)

A

`12.42xx10^(-21)J, 968 m//s`

B

`8.78xx10^(-21)J, 684 m//s`

C

`6.21xx10^(-21)J, 968m//s`

D

`12.42xx10^(-21)J, 684m//s`

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The correct Answer is:
To find the average translational energy and the root mean square (rms) speed of molecules in a sample of oxygen gas at `600K`, we can use the following relationships for an ideal gas: 1. **Average Translational Energy (E_avg)**: The average translational energy of a gas molecule is given by the formula: \[ E_{\text{avg}} = \frac{3}{2} k T \] where \( k \) is the Boltzmann constant (\( k \approx 1.38 \times 10^{-23} \, \text{J/K} \)) and \( T \) is the temperature in Kelvin. 2. **Root Mean Square Speed (v_{rms})**: The rms speed of gas molecules is given by the formula: \[ v_{\text{rms}} = \sqrt{\frac{3kT}{m}} \] where \( m \) is the mass of a gas molecule. ### Step 1: Calculate Average Translational Energy at 600K Using the average translational energy formula: \[ E_{\text{avg}}(600K) = \frac{3}{2} k (600) \] Substituting \( k \): \[ E_{\text{avg}}(600K) = \frac{3}{2} (1.38 \times 10^{-23}) (600) \] Calculating this gives: \[ E_{\text{avg}}(600K) = \frac{3}{2} (8.28 \times 10^{-21}) \approx 1.24 \times 10^{-20} \, \text{J} \] ### Step 2: Calculate RMS Speed at 600K Using the rms speed formula: \[ v_{\text{rms}}(600K) = \sqrt{\frac{3k(600)}{m}} \] We know that the rms speed at 300K is 484 m/s. The rms speed is proportional to the square root of the temperature: \[ v_{\text{rms}}(600K) = v_{\text{rms}}(300K) \sqrt{\frac{600}{300}} = 484 \sqrt{2} \] Calculating this gives: \[ v_{\text{rms}}(600K) = 484 \times 1.414 \approx 684 \, \text{m/s} \] ### Final Results - Average Translational Energy at 600K: \( \approx 1.24 \times 10^{-20} \, \text{J} \) - RMS Speed at 600K: \( \approx 684 \, \text{m/s} \)

To find the average translational energy and the root mean square (rms) speed of molecules in a sample of oxygen gas at `600K`, we can use the following relationships for an ideal gas: 1. **Average Translational Energy (E_avg)**: The average translational energy of a gas molecule is given by the formula: \[ E_{\text{avg}} = \frac{3}{2} k T \] where \( k \) is the Boltzmann constant (\( k \approx 1.38 \times 10^{-23} \, \text{J/K} \)) and \( T \) is the temperature in Kelvin. ...
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