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Valence-bond theory is one of the two qu...

Valence-bond theory is one of the two quantum mechanical approaches that explains bonding in molecules In some cases, valence bond theroy cannot cannot satisfactorily account for observed properties of molecules
Consider the following molecular geometries
`{:(NO,,CO,,O_(2)):}`
Select correct statement`(s)` about these (More than one correct) .

A

`NO` is paramagnetic `CO` and `O_(2)` are diamagnetic

B

`NO` and `O_(2)` are paramagnetic `CO` is diamagentic

C

Bond order is in order `O_(2) lt NO lt CO`

D

Number of unpaired electrons are
`{:(NO,,1,,),(CO,,0,,),(O_(2),,0,,):}`

Text Solution

Verified by Experts

The correct Answer is:
B, C

Bond order of `NO,O_(2)` and `CO` and `CO` are 1,2 and 0 respectively Hence `NO` and `H_(2)` are paramagnetic `CO` is diamagentic Statement (b) is correct .
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CENGAGE CHEMISTRY-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Linked Comprehension
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  2. The HF(2)^(Θ) ion solid state and in liquid HF but not in the dilute a...

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  3. The HF(2)^(Θ) ion solid state and in liquid HF but not in the dilute a...

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  4. The HF(2)^(Θ) ion solid state and in liquid HF but not in the dilute a...

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  5. Valence-bond theory is one of the two quantum mechanical approaches th...

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  6. Valence-bond theory is one of the two quantum mechanical approaches th...

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  8. Valence-bond theory is one of the two quantum mechanical approaches th...

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  9. Valence-bond theory is one of the two quantum mechanical approaches th...

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  10. According to the moleular orbital theory, all atomic orbitals combine ...

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  11. According to the moleular orbital theory, all atomic orbitals combine ...

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  12. According to the moleular orbital theory, all atomic orbitals combine ...

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  13. Most of the polyatomic molecules except a few such as CO(2) and CS(2) ...

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  14. Most of the polyatomic molecules except a few such as CO(2) and CS(2) ...

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  15. Most of the polyatomic molecules except a few such as CO(2) and CS(2) ...

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  16. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  17. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  18. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  19. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  20. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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