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Boric acid on heating at 100^@ C, gives ...

Boric acid on heating at `100^@ C`, gives `(X)`. `(X)` on heating at `160^@ C` gives `(Y)` and `(Y)` on heating at red hot gives `(Z)`. Identify `(X),(Y)` and `(Z)`.

Text Solution

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`H_(3) BO_(3) overset(100^@C)rarr underset("Metaboric acid (X)") (HBO_(2)) + H_(2) O`
`4HBO_(2) overset(160^@C)rarr underset("Tetraboric acid(Y)")(H_(2) B_(4) O_(7)) + H_(2) O`
`H_(2)B_(4) O_(7) overset("Red hot")rarr underset((Z)) (B_(2) O_(3)) + H_(2) O`
Hence, `(X)` is metaboric acid, `HBO_(2)` , `(Y)` is tetraboric acid, `H_(2) B_(4) O_(7)` and `(Z)` is boric oxide, `B_(2) O_(3)`.
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