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DeltaG^(Ө) vs T plot in Ellingham diagra...

`DeltaG^(Ө)` vs T plot in Ellingham diagram slopes downward for the reaction .

A

`Mg + (1)/(2) O_(2) rarr MgO`

B

`2Ag + (1)/(2) O_(2) rarr Ag_(2) O`

C

`C + (1)/(2) O_(2) rarr CO`

D

`CO + (1)/(2) O_(2) rarr CO_(2)`

Text Solution

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The correct Answer is:
C

`C(s) + (1)/(2) O_(2(g)) rarr CO_((g)) , Delta S` increase. Hence, as the temperature increases, `T Delta S` increases and hence `Delta G(Delta H - T Delta S)` decreases. In other words. The slope of the curve for formation of `CO` decreases. Howeve, for all other oxides, it increases.
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