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Sulphur on reaction with concentrated HN...

Sulphur on reaction with concentrated `HNO_3`. Gives `(A)` which reacts with reacts with `NaOH` gives `(B).(A)` and `(B)` are

A

`H_2 SO_3, Na_2 S_2 O_3`

B

`NO_2, Na_2 S`

C

`H_2 SO_4, Na_2 SO_4`

D

`H_2 S_2 O_3, Na_2 S_2 O_3`

Text Solution

Verified by Experts

The correct Answer is:
C

`S + HNO_(3) rarr (A)`
`(A) + overset(conc.) (NaOH) rarr (B)`
`S + 6 HNO_(3) rarr underset((A))(H_(2) SO_(4) + 6 NO_(2) + 2 H_(2) O`
`underset((A)) (H_(2) SO_(4)) + 2 NaOH rarr Na_(2) SO_(4) + 2 H_(2) O`.
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