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Sulphur and rest of the elements of grou...

Sulphur and rest of the elements of group `16` are less electronegative than oxygen, Therefore, their atoms cannot take electrons easily. They can acquire `ns^2 np^6` configuration by sharing two electrons with the atoms of other elements and thus, exhibit `+2` oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the `p` and s-orbitals of the same shell. As a result, they can show `+4` and `+ 6` oxidation states.
Like sulphur, oxygen does not show `+ 4` and `+6` oxidation states. The reason is

A

That oxygen is a gas while sulphur is a solid

B

That oxygen has high ionisatio enthalpies in comparison to sulphur

C

That oxygen has high electron affinity in comparison to sulphur

D

That oxygen has no d-orbitals in its valence shell.

Text Solution

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The correct Answer is:
D
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Sulphur and rest of the elements of group 16 are less electronegative than oxygen, Therefore, their atoms cannot take electrons easily. They can acquire ns^2 np^6 configuration by sharing two electrons with the atoms of other elements and thus, exhibit +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the p and s-orbitals of the same shell. As a result, they can show +4 and + 6 oxidation states. Oxygen exhibits +2 oxidation state in

Sulphur and rest of the elements of group 16 are less electronegative than oxygen, Therefore, their atoms cannot take electrons easily. They can acquire ns^2 np^6 configuration by sharing two electrons with the atoms of other elements and thus, exhibit +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the p and s-orbitals of the same shell. As a result, they can show +4 and + 6 oxidation states. The oxidation state of sulphur in Na_2 S_4 O_6 is

Sulphur and rest of the elements of group 16 are less electronegative than oxygen, Therefore, their atoms cannot take electrons easily. They can acquire ns^2 np^6 configuration by sharing two electrons with the atoms of other elements and thus, exhibit +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the p and s-orbitals of the same shell. As a result, they can show +4 and + 6 oxidation states. The nature of the compounds of sulphur having +4 oxidation state is

Sulphur and rest of the elements of group 16 are less electronegative than oxygen, Therefore, their atoms cannot take electrons easily. They can acquire ns^2 np^6 configuration by sharing two electrons with the atoms of other elements and thus, exhibit +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the p and s-orbitals of the same shell. As a result, they can show +4 and + 6 oxidation states. The oxidation state of of sulphur in S_8, SO_3 and H_2 S respectively are.

Which of the following atom with outer electronic configuration exhibit maximum oxidation state ?

What is the general name of the elements having 8 electrons in the valence shell of their atoms ?

Valence electrons in the atom of element A is 4 and in the element B is 2. Most probable compound formed from A and B is

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  15. The binary compounds of oxygen with other elements are called oxides. ...

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