Home
Class 12
CHEMISTRY
(a) Fluorine cannot be prepared from flu...

(a) Fluorine cannot be prepared from fluorides by chemical oxidation. Why?
(b) Anhydrous `HCl` is bad conductor of electricity while aqueous `HCl` is a good conductor. Give reason.
(c ) Fresh iodine stain can be removed by washing with hypo solution. Explain.

Text Solution

Verified by Experts

(a) The standard reduction potential of fluorine is maximum. Thus, it cannot be oxidised by any other reagent. Fluoride ion is very stable due to small size and high electronegativity of fluorine atom. Thus, fluorine cannot be prepared from fluorides by chemical oxidation.
(b) In anhydrous state, `HCl` is a covalent molecule, hence bad conductor of electricity. Whereas , in aqueous state, `HCl` ionises and acts as good conductor.
`HCl+H_(2)O rarr H_(3)O^(o+)+Cl^(Ө)`
(c ) Hypo solution i.e. sodium thiosulphate, `Na_(2)S_(2)O_(3).5H_(2)O` reacts with iodine to form water soluble colourless sodium tetrathionate and sodium iodide.
`{:(2Na_(2)S_(2)O_(3)+I_(2)to2NaI+Na_(2)S_(4)O_(6)),(or 2S_(2)O_(3)^(2-)toS_(4)O_(6)^(2-)+2e^(Ө)),(I_(2)+2e^(Ө)to2I^(Ө)),(ulbar(2S_(2)O_(3)^(2-)+I_(2)toS_(4)O_(6)^(2-)+2I^(Ө))):}`
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY

    CENGAGE CHEMISTRY|Exercise Solved Example|7 Videos
  • P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY

    CENGAGE CHEMISTRY|Exercise Exs 4.1 (Subjective)|16 Videos
  • P-BLOCK GROUP 16 ELEMENTS - THE OXYGEN FAMILY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|10 Videos
  • P-BLOCK GROUP 18 ELEMENTS - THE INERT GASES

    CENGAGE CHEMISTRY|Exercise Ex 5.1 (Objective)|14 Videos

Similar Questions

Explore conceptually related problems

Give reasons in one or two sentences "Anhydrous HCl is a bad conductor of electricity but aqueous HCl is a good conductor".

Given reasons in one or two sentences. “Anhydrous HCl is a bad conductor of electricity but aqueous HCl is a good conductor.”

Give reasons in one or two sentences :" anhydrous HCl is a bad conductor of electricity but aqueous HC l is a good conductor. "

Explain the following with proper reason: (i) Anhydrous HCl is a bad conductor of electricity while aqueous HCl is a good conductor. (ii) HF is not stored in glass bottles but kept in wax lined bottles. (iii) HF has a greater electronegativity difference and more ionic character than HCI, HBr and Hl but it the weakest acid.

Explain the following with proper reasons : (i) Fluorine cannot be prepared from fluorides by chemical oxidation. (ii) Fluorine does not from F_3^- (polyhalide) ion