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Consider the following experiments and a...

Consider the following experiments and answer the questions at the end of it
(A) When `Fe(CN)_(2)` solution is treated with `KCN` solution species formed no longer gives tests of `Fe^(2+)` and `CN^(Θ)`
(B) When `K_(2)SO_(4)` solution is treated with `A1_(2)(SO_(4))_(3)` solution species formed gives tests of `K^(o+),A1^(3+)` and `SO_(4)^(2-)`
Species formed in experiment `A` does not give test of `Fe^(2+)` and `CN^(Θ)` it is due to formation of .

A

`K_(2)[Fe(CN)_(4)]`

B

`K_(3)[Fe(CN)_(5)]`

C

`K_(3)[Fe(CN)_(6)]`

D

`K_(4)[Fe(CN)_(6)]`

Text Solution

Verified by Experts

The correct Answer is:
D

`Fe(CN)_(2)+4KCNrarrK_(4)[Fe(CN)_(6)]`
(Complex compounds)
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Consider the following experiments and answer the questions at the end of it (A) When Fe(CN)_(2) solution is treated with KCN solution species formed no longer gives tests of Fe^(2+) and CN^(Θ) (B) When K_(2)SO_(4) solution is treated with A1_(2)(SO_(4))_(3) solution species formed gives tests of K^(o+),A1^(3+) and SO_(4)^(2-) Species formed in experiment (B) is .

Consider the following experiments and answer the questions at the end of it (A) When Fe(CN)_(2) solution is treated with KCN solution species formed no longer gives tests of Fe^(2+) and CN^(Θ) (B) When K_(2)SO_(4) solution is treated with A1_(2)(SO_(4))_(3) solution species formed gives tests of K^(o+),A1^(3+) and SO_(4)^(2-) EAN of iron formed in (A) is .

Consider the following experiments and answer the questions at the end of it (A) When Fe(CN)_(2) solution is treated with KCN solution species formed no longer gives tests of Fe^(2+) and CN^(Θ) (B) When K_(2)SO_(4) solution is treated with A1_(2)(SO_(4))_(3) solution species formed gives tests of K^(o+) ,A1^(3+) and SO_(4)^(2-) When the species formed in A is treated with FeCI_(3) a bule colour is obtained It is due to formation of .

Aqueous solution of Fe SO_4 gives tests for both Fe^(2+) and SO_4^(2-) but after addition of excess of KCN, solution ceases to give test for Fe^(2+) . This is due to the formation of:

Alum in aqueous solution gives positive test for (A) K^(+) (B) Al^(3+) (C) SO_(4)^(2-)

Addition of K_(4)[Fe(CN)_(6)] solution to FeCl_(3) solution gives

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