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Consider the following experiments and a...

Consider the following experiments and answer the questions at the end of it
(A) When `Fe(CN)_(2)` solution is treated with `KCN` solution species formed no longer gives tests of `Fe^(2+)` and `CN^(Θ)`
(B) When `K_(2)SO_(4)` solution is treated with `A1_(2)(SO_(4))_(3)` solution species formed gives tests of `K^(o+)`,A1^(3+)` and `SO_(4)^(2-)`
When the species formed in `A` is treated with `FeCI_(3)`a bule colour is obtained It is due to formation of .

A

`Fe^(II) [Fe^(III)(CN)_(6))]^(Θ)`

B

`Fe^(II) [Fe^(III)(CN)_(6))]^(Θ)`

C

Both(a)and(b)

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C

Blue colour is a mixture of Prussian blue and Turnbull's blue. [Refer Note in Section 7.17 (Point2)] .
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Consider the following experiments and answer the questions at the end of it (A) When Fe(CN)_(2) solution is treated with KCN solution species formed no longer gives tests of Fe^(2+) and CN^(Θ) (B) When K_(2)SO_(4) solution is treated with A1_(2)(SO_(4))_(3) solution species formed gives tests of K^(o+),A1^(3+) and SO_(4)^(2-) Species formed in experiment (B) is .

Consider the following experiments and answer the questions at the end of it (A) When Fe(CN)_(2) solution is treated with KCN solution species formed no longer gives tests of Fe^(2+) and CN^(Θ) (B) When K_(2)SO_(4) solution is treated with A1_(2)(SO_(4))_(3) solution species formed gives tests of K^(o+),A1^(3+) and SO_(4)^(2-) EAN of iron formed in (A) is .

Consider the following experiments and answer the questions at the end of it (A) When Fe(CN)_(2) solution is treated with KCN solution species formed no longer gives tests of Fe^(2+) and CN^(Θ) (B) When K_(2)SO_(4) solution is treated with A1_(2)(SO_(4))_(3) solution species formed gives tests of K^(o+),A1^(3+) and SO_(4)^(2-) Species formed in experiment A does not give test of Fe^(2+) and CN^(Θ) it is due to formation of .

When K_(4)[Fe(CN)_(6)] is treated with FeCI_(3) a blue colour is obtained It is due to the formation of .

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