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Among the following ions which has the h...

Among the following ions which has the highest paramagntism ? .

A

`[Cr(H_(2)O)_(6)]^(3+)`

B

`[Fe(H_(2)O)_(6)]^(2+)`

C

`[Cu(H_(2)O)_(6)]^(2+)`

D

`[Zn(H_(2)O)_(6)]^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
b

`[Co(H_(2)O)_(6)]^(3+) Cr(Z =24) implies 3d^(5) 4s^(1)`
There are three unpaired electrons
(ii) `[Fe(H_(2)O)_(6)]_(2)` has the maximum number of unpaired electrons, therefore the highest degree of paramagnetism
(iv) `[Cu(H_(2)O)_(6)^(2+) , Cu(Zn =29)implies3d^(10) 4d^(1), Cu^(2+) = 3d^(9)`
There is unpaired electrons
(v) `[Zn(H_(2)O)_(6)]^(2+),Zn (z =30) implies 3d^(10) 4s^(2) , Zn^(2+) =3d^(10)`
Threr are no unpaired electrons



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