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Among the following complexes (K-P) K(...

Among the following complexes `(K-P)`
`K_(3)[Fe(CN)_(6)](K),[Co(Nh_(3))_(6)]CI_(3)(L)`
`Na_(3)[Co(oxalate)_(3)](M),[Ni(H_(2)O)_(6)]CI_(2)(N)`
`[Pt(CN)_(4)](O)` and `[Zn(H_(2)O)_(6)(NO_(3)_(2)(P)`
The diamagnetic are .

A

`K,L,M,N`

B

`K,M,O,P`

C

`L,M,O,P`

D

`L,M,N,O`

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The correct Answer is:
To determine which of the given complexes are diamagnetic, we need to analyze the electronic configurations of the central metal ions in each complex and count the number of unpaired electrons. A complex is diamagnetic if it has no unpaired electrons (n = 0). ### Step-by-Step Solution: 1. **Analyze K3[Fe(CN)6] (K)**: - Central atom: Iron (Fe) - Atomic number of Fe: 26 - Electronic configuration: 3d^6 4s^2 - Oxidation state in the complex: +3 - Electronic configuration in +3 state: 3d^5 4s^0 - CN is a strong field ligand, causing pairing of electrons. - Configuration after pairing: 3d^5 (1 unpaired electron) - **Result**: Paramagnetic (n = 1) 2. **Analyze [Co(NH3)6]Cl3 (L)**: - Central atom: Cobalt (Co) - Atomic number of Co: 27 - Electronic configuration: 3d^7 4s^2 - Oxidation state in the complex: +3 - Electronic configuration in +3 state: 3d^6 4s^0 - NH3 is a strong field ligand, causing pairing of electrons. - Configuration after pairing: 3d^6 (0 unpaired electrons) - **Result**: Diamagnetic (n = 0) 3. **Analyze Na3[Co(oxalate)3] (M)**: - Central atom: Cobalt (Co) - Oxidation state in the complex: +3 - Similar to the previous complex, Co is in +3 state: 3d^6 4s^0 - Oxalate is also a strong field ligand, causing pairing of electrons. - Configuration after pairing: 3d^6 (0 unpaired electrons) - **Result**: Diamagnetic (n = 0) 4. **Analyze [Ni(H2O)6]Cl2 (N)**: - Central atom: Nickel (Ni) - Atomic number of Ni: 28 - Electronic configuration: 3d^8 4s^2 - Oxidation state in the complex: +2 - Electronic configuration in +2 state: 3d^8 4s^0 - H2O is a weak field ligand, causing no pairing of electrons. - Configuration: 3d^8 (2 unpaired electrons) - **Result**: Paramagnetic (n = 2) 5. **Analyze [Pt(CN)4] (O)**: - Central atom: Platinum (Pt) - Atomic number of Pt: 78 - Electronic configuration: 5d^9 6s^1 - Oxidation state in the complex: +2 - Electronic configuration in +2 state: 5d^8 6s^0 - CN is a strong field ligand, causing pairing of electrons. - Configuration after pairing: 5d^8 (0 unpaired electrons) - **Result**: Diamagnetic (n = 0) 6. **Analyze [Zn(H2O)6](NO3)2 (P)**: - Central atom: Zinc (Zn) - Atomic number of Zn: 30 - Electronic configuration: 3d^10 4s^2 - Oxidation state in the complex: +2 - Electronic configuration in +2 state: 3d^10 4s^0 - Configuration: 3d^10 (0 unpaired electrons) - **Result**: Diamagnetic (n = 0) ### Final Results: The diamagnetic complexes among the given options are: - [Co(NH3)6]Cl3 (L) - Na3[Co(oxalate)3] (M) - [Pt(CN)4] (O) - [Zn(H2O)6](NO3)2 (P)

To determine which of the given complexes are diamagnetic, we need to analyze the electronic configurations of the central metal ions in each complex and count the number of unpaired electrons. A complex is diamagnetic if it has no unpaired electrons (n = 0). ### Step-by-Step Solution: 1. **Analyze K3[Fe(CN)6] (K)**: - Central atom: Iron (Fe) - Atomic number of Fe: 26 - Electronic configuration: 3d^6 4s^2 ...
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Among the following complexes (K – P), K_3[Fe(CN)_6] (K), [Co(NH_3)6]Cl_3 (L), Na_3[Co(oxalate)_3] (M), [Ni(H_2O)_6]Cl_2(N), K_2[Pt(CN)_4] (O) and [Zn(H_2O)_6](NO_3)_2 (P) the diamagnetic complexes are

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