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H(2)S will precipitate the sulphide of a...

`H_(2)S` will precipitate the sulphide of all the metals from the solution of chlorides of `Cu,Zn and Cd` if

A

The solution is aqueous

B

The solution is acidic

C

The solution is diute acidic

D

Any of the above solution is present

Text Solution

Verified by Experts

The correct Answer is:
a

`H_(2)S` in neutral medium provides sufficient `S^(2-)` to precipitate `Cu,Cd,Zn, and Mn `as sulphide
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Consider the following statement: S_(1) : Cu^(2+) ions are reduced to Cu^(+) by potassium iodide and potassium cyanide both, when taken in excess S_(2) : H_(2)S will precipitate the sulphide of all the metals from the solutions of chlorides of Cu,Zn and Cd if the solution is aqueous. S_(3) :The presence of magnesium is confirmed in qualitative analysis by the formation of a white crystal S_(4) :Calomel on reaction with potassium iodide gives red precipitate. and arrange in the order of true/false.

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CENGAGE CHEMISTRY-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Single Correct) Part-C (Analysis Of Cations)
  1. Nitric acid is generally not used for prepation of original solution ...

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  2. The sulphide not soluble in hot dilute nitric acid is

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  3. H(2)S will precipitate the sulphide of all the metals from the soluti...

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  4. To a solution of a substance gradiual addition of ammonium hydroxide...

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  5. A compound is soluble in water if ammonia is added to aqeous solution...

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  6. A light green salt soluble in water gives black precipitate on passi...

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  7. All ammonium salt liberate ammonia when

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  8. Manganese salt + PbO(2) + conc. HNO(2) rarr The solution has purple ...

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  9. An orange precipitate of group II is dissolve in cone HCI the solutio...

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  10. Which of the following solution gives precipitate with Pb(NO(3))(2) bu...

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  11. A white powder when strongly heated gives off brown forms A solution...

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  12. The ion that cannot be precipitate by both HCI and H(2)S is

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  13. The presence of magnessium is confimed in the qualitative amalysis by ...

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  14. In qualitative inorganic amalysis phosphan , if present is to be eleme...

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  15. Na(2)CO(3) cannot be used in place of (NH(4))(2)CO(3) for the precipit...

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  16. Disodium hydrogen phosphate is used in test :

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  17. Raddish - brown (chocolate ) ppt. is formed with :

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  18. Addition of SnCl(2) to HgCI(2) gives ppt. :

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  19. To avoid the precipitate of hydroxide of Ni^(2+),Co^(2+),Zn^(2+) and M...

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  20. Which give a white precipitate with a solution of AgNO(3) is white pr...

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