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To avoid the precipitate of hydroxide of...

To avoid the precipitate of hydroxide of `Ni^(2+),Co^(2+),Zn^(2+)` and `Mn^(2+)` along with these of `Fe^(3+),Al^(3+)` and `Cr^(3+)` the third group solution should be

A

Heated with a few drop of cone `HNO_(3)`

B

Treated with excess of `NH_(4)CI`

C

Conccotrated

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
b

The presence of `NH_(4)CI` in excess reducts degree of dissociation of `NH_(4)OH` to a considerable amount and thas `[OH^(Theta)]` just sufficient to cross ever the and ionic concentration product of hyddroxide of group III elements to their `K_(sp)`
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To avoid the precipitation of hydroxides of Ni^(2+),Co^(2+),Zn^(2+) and Mn^(2+) along with those of Fe^(3+),Al^(3+) and Cr^(3+) the third group solution should be:

To avoid the precipitation of hydroxides of Ni^(2+),Co^(2+),Mn^(2+) along with those of the third group cations, the solutions should be:

Which of the following arrangements does not represent the correct order of the property stated against it ? (i) Ni^(2+) lt Co^(2+) lt Fe^(2+) lt Mn^(2+) : ionic size (ii) Co^(3+) lt Fe^(3+) lt Cr^(3+) lt Sc^(3+) : stability in aqueious solution (iii) Sc lt Ti lt Cr lt Mn : number of oxidation states (iv) V^(2+) lt Cr^(2+) lt Mn^(2+) lt Fe^(2+) : paramagnetic behaviour

which is are correct statement for following : Mn^(+4),Cr^(+2),Ni^(+2),Zn^(+2)

Of the ions Zn^(2), Ni^(2 +) and Cr^(3 +) [atomic number of Zn = 30, Ni = 28, Cr = 24 ]

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