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What is the significance of leaching in the extraction of aluminium?

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The principal ore of aluminium is bauxite. It usually contains silica `(SiO_2)`. Iron oxide `(Fe_2O_3)` and titanium oxide `(TiO_20` as impurities. These impurities can be removed by the process of leaching. During leaching, the powdered bauxite ore is heated with a concentrated `(45%)` solution of `NaOH` at `473-523K`, when alumina dissolves as sodium metaaluminate and silica `(SiO_2)` as sodium silicate leaving `Fe_2O_3,TiO_2` and other impurities behind.
`Al_2O_3+2NaOH+3H_2Ooverset(473-523K)to2Na[Al(OH)_4]`
`SiO_2+2NaOHoverset(473-523K)toNaSiO_3+H_2O_(1)`
The impurities are filtered off and the solution of sodium metaaluminate is neutralised by passing `CO_2` when hydrated alumine separates out while sodium silicate remains in the solution.
`2Na[Al(OH)_4]_(aq)+2CO_2toAl_2O_3.xH_2Odarr2NaHCO_3`
the hydrated alumina thus obtained is filtered, dried and heated to give back pure alumina.
`Al_2O_3+xH_2O`
Thus the significance of leaching in the extraction of aluminium is to prepare pure alumina from the bauxite ore
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CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Short Answer Type
  1. What is the significance of leaching in the extraction of aluminium?

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  2. Which metals are generally extracted by the electrolytic processes ? W...

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  3. What type of ores are roasted?

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  4. Give the names of the four most abundant elements in the earth's crust...

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  5. What is a mineral? How does it differ from an ore?

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  6. Why do some metals occur in the native state?

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  7. Name the method used for refining of : (a). Zirconium. (b). Nickel...

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  8. Can iron be purified by amalgamation?

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  9. Both iron and aluminium combine slowly with oxygen at room temperature...

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  10. What is the name given to solid phase of earth?

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  11. Give one example where hydrometallurgy is used for metal extraction?

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  12. Name the method of metal refining which is generally used when a metal...

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  13. When is electrolytic reduction applied for getting a metal?

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  14. What name is given to carbon reduction process for extracting the meta...

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  15. An ore has impurities which are attracted by magnet suggest process fo...

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  16. In moist air, copper corrodes to produce a green layer on the surface....

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  17. The value of triangle(f)G^(ɵ)(Cr2O3)=-540kJmol^-1 and triangle(f)G^(ɵ)...

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  18. What do you understand by roasting in presence of NaCl?

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  19. Why NF3 cannot be hydrolysed, while NCl3 can be readily hydrolysed?

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  20. Why NI5 does not exist While PCl5 exists?

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  21. Why the boiling point of ammonia is greater than phosphine?

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