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Why Sm^(2+) , Eu^(2+) and Yb^(2+) ions i...

Why `Sm^(2+) , Eu^(2+)` and `Yb^(2+)` ions in solution are good reducing agent but an aqueous solution of `Ce^(4+)` is a good oxidising agent?

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The most stable oxidation state of lanthanides is `+3`. Hence, ions in `+2` state tend to change to `+3` state by loss of electron and those in `+4` state tend to change to `+3` state by gain of electron.
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CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Short Answer Type
  1. Scandium forms no coloured ions, yet it is regarded as a transition el...

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  2. Assertion : Hydrochloric acid is not used to acidify a KMnO(4) solutio...

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  3. Why Sm^(2+) , Eu^(2+) and Yb^(2+) ions in solution are good reducing a...

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  4. Why is the separation of lanthanide elements difficult?

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  5. The second ionisation enthalpies of both Cr and Cu are higher than tho...

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  6. Name the compound used for measuring the hardness of water, i.e., for ...

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  7. How will you distinguish between the following isomer pairs? (a). (i...

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  8. The magnitude of stability constant gives an indication of the stabili...

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  9. What are the most common coordination numbers encountered in coordinat...

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  10. Name the central atom present in haemoglobin and chlorophyll.

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  11. Wilkinson's catalyst is used as a homogeneous hydrogenation catalyst f...

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  12. What is spectrochemical series?

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  13. What is crystal field splitting energy? How does the magnitude of tria...

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  14. What are t(2g) and e(g) orbitals?

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  15. Give the geometry and magnetic character of [NiBr4]^(2-)

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  16. How is tetrabutyl tim prepared?

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  17. What is te coordination number of Fe in [Fe(EDTA)]^(ɵ)?

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  18. Name the two broad categories of organometallic compounds.

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  19. In the formula Fe(eta^(5)-C5H5), what does the prefix eta^(5) denote?

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  20. Give names of two complexes which are used in medicines.

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