Home
Class 12
CHEMISTRY
Explain [Co(NH3)6]^(3+) is an inner orbi...

Explain `[Co(NH_3)_6]^(3+)` is an inner orbital complex whereas `[Ni(NH_3)_6]^(2+)` is an outer orbital complex.

Text Solution

AI Generated Solution

To explain why `[Co(NH_3)_6]^(3+)` is an inner orbital complex while `[Ni(NH_3)_6]^(2+)` is an outer orbital complex, we need to analyze the electronic configurations and hybridization of the central metal ions in each complex. Here is a step-by-step solution: ### Step 1: Determine the oxidation states and electronic configurations of the central metal ions. - **Cobalt in `[Co(NH_3)_6]^(3+)`:** - Cobalt (Co) has an atomic number of 27. Its ground state electronic configuration is `[Ar] 3d^7 4s^2`. - In the +3 oxidation state, cobalt loses 3 electrons. The configuration becomes: \[ ...
Promotional Banner

Topper's Solved these Questions

  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY|Exercise Exercises|126 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY|Exercise Short Answer Type|179 Videos
  • AMINES

    CENGAGE CHEMISTRY|Exercise QUESTION BANK|1 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

The questions given below consist of Assertion (A) and Reason (R ) . Use the following key to select the correct answer. [FeF_6]^(4-) is a paramagnetic complex while [Fe(CN)_6^(4-)] is a diamagnetic complex . Reason : [FeF_6]^(4-) is an outer orbital complex whereas [Fe(CN)_6]^(4-) is an inner orbital complex .

[Co(F)_(6)]^(3-) ' forms outer orbital complexes while [Co(CN)_(6)]^(3-) forms inner orbital complexes

[CoF_(6)]^(3-) forms outer orbital complexes while (Co(CN)_(6)]^(3-) forms inner orbital complexes. Why

In the following questions , a statement of assertion (A) is followed by a statement of reason (R). A: [Co(NH_3)_6]^(+3) is a diamagnetic complex. R: [Co(NH_3)_6]^(+3) is a octahedral shape.

A: [Cr (H_(2)O)_(6)]^(3+) is Inner orbital complex. R: H_(2)O is strong ligand generally

What is the IUPAC name of complex [Ni(NH_3)_6]Cl_2 ?

Assertion: Complex ion [Co(NH_(3))_(6)]^(2+) is readily oxidized to [Co(NH_(3))_(6)]^(3+) Reason: Unpaired electron in complex ion [Co(NH_(3))_(6)]^(2+) is present in 4p orbital.

CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Short Answer Type
  1. Explain [Co(NH3)6]^(3+) is an inner orbital complex whereas [Ni(NH3)6]...

    Text Solution

    |

  2. Which metals are generally extracted by the electrolytic processes ? W...

    Text Solution

    |

  3. What type of ores are roasted?

    Text Solution

    |

  4. Give the names of the four most abundant elements in the earth's crust...

    Text Solution

    |

  5. What is a mineral? How does it differ from an ore?

    Text Solution

    |

  6. Why do some metals occur in the native state?

    Text Solution

    |

  7. Name the method used for refining of : (a). Zirconium. (b). Nickel...

    Text Solution

    |

  8. Can iron be purified by amalgamation?

    Text Solution

    |

  9. Both iron and aluminium combine slowly with oxygen at room temperature...

    Text Solution

    |

  10. What is the name given to solid phase of earth?

    Text Solution

    |

  11. Give one example where hydrometallurgy is used for metal extraction?

    Text Solution

    |

  12. Name the method of metal refining which is generally used when a metal...

    Text Solution

    |

  13. When is electrolytic reduction applied for getting a metal?

    Text Solution

    |

  14. What name is given to carbon reduction process for extracting the meta...

    Text Solution

    |

  15. An ore has impurities which are attracted by magnet suggest process fo...

    Text Solution

    |

  16. In moist air, copper corrodes to produce a green layer on the surface....

    Text Solution

    |

  17. The value of triangle(f)G^(ɵ)(Cr2O3)=-540kJmol^-1 and triangle(f)G^(ɵ)...

    Text Solution

    |

  18. What do you understand by roasting in presence of NaCl?

    Text Solution

    |

  19. Why NF3 cannot be hydrolysed, while NCl3 can be readily hydrolysed?

    Text Solution

    |

  20. Why NI5 does not exist While PCl5 exists?

    Text Solution

    |

  21. Why the boiling point of ammonia is greater than phosphine?

    Text Solution

    |