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Consider the Hofmann ammonolysis reactio...

Consider the Hofmann ammonolysis reaction :
`R-X +ddotNH_(3)rarr underset(1^(@) amine)(HX + RNH_(2)) overset(R-X)underset(373K)rarr`

If `R = Me_3 C - (t-butyl)`, the correct order of basic character of the above amines in aqueous medium is :

A

`NH_3 gt 1^@ gt 2^@ gt 3^@`

B

`3^@ gt 2^@ gt 1^@ gt NH_3`

C

`1^@ gt 2^@ gt NH_3 gt 3^@`

D

`1^@ gt NH_3 gt 2^@ gt 3^@`

Text Solution

Verified by Experts

The correct Answer is:
A
(a) In gaseous or nonpolar solvent, the basic order is `3^@ gt 2^@ gt 1^@ gt NH_3`.
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