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The leaving group is that functional gro...

The leaving group is that functional group which is ejected with `overline e^, s` of the `sigma` -bond in a reaction. Better the leaving group, faster is the reaction. The relative leaving ability of the leaving group `X` in `(R - X)` is increased by :
(i) The polarisability of `(R - X)` bond.
(ii) The stability of `X^(Ө)`.
(iii) The degree of stabilisation through solvation of `X`.
(iv) The strength of `(R - X)` bond.
The leaving group tendency is also called fugacity.
Which one of the followingd has the highest fugacity ?

A

Tosylate `(overset (Ө) O Ts)`

B

Mesylate

C

Triflate `(F_3 C - SO_3^(Ө))`

D

All are equal

Text Solution

Verified by Experts

The correct Answer is:
C

It is the conjugate base (weak base) of the strongest acid `(F_3 C - SO_3 H)`.
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The leaving group is that functional group which is ejected with overline e^, s of the sigma -bond in a reaction. Better the leaving group, faster is the reaction. The relative leaving ability of the leaving group X in (R - X) is increased by : (i) The polarisability of (R - X) bond. (ii) The stability of X^(Ө) . (iii) The degree of stabilisation through solvation of X . (iv) The strength of (R - X) bond. The leaving group tendency is also called fugacity. Which of the following undergoes SN reaction easily ?

The leaving group is that functional group which is ejected with overline e^, s of the sigma -bond in a reaction. Better the leaving group, faster is the reaction. The relative leaving ability of the leaving group X in (R - X) is increased by : (i) The polarisability of (R - X) bond. (ii) The stability of X^(Ө) . (iii) The degree of stabilisation through solvation of X . (iv) The strength of (R - X) bond. The leaving group tendency is also called fugacity. Which statement is wrong ?

The leaving group is that functional group which is ejected with overline e^, s of the sigma -bond in a reaction. Better the leaving group, faster is the reaction. The relative leaving ability of the leaving group X in (R - X) is increased by : (i) The polarisability of (R - X) bond. (ii) The stability of X^(Ө) . (iii) The degree of stabilisation through solvation of X . (iv) The strength of (R - X) bond. The leaving group tendency is also called fugacity. Which statement is correct ?

The leaving group is that functional group which is ejected with overline e^, s of the sigma -bond in a reaction. Better the leaving group, faster is the reaction. The relative leaving ability of the leaving group X in (R - X) is increased by : (i) The polarisability of (R - X) bond. (ii) The stability of X^(Ө) . (iii) The degree of stabilisation through solvation of X . (iv) The strength of (R - X) bond. The leaving group tendency is also called fugacity. Which statement is correct ?

The leaving group is that functional group which is ejected with overline e^, s of the sigma -bond in a reaction. Better the leaving group, faster is the reaction. The relative leaving ability of the leaving group X in (R - X) is increased by : (i) The polarisability of (R - X) bond. (ii) The stability of X^(Ө) . (iii) The degree of stabilisation through solvation of X . (iv) The strength of (R - X) bond. The leaving group tendency is also called fugacity. Which of the following is the wrong order of fugacity ?

The correct order of the ability of the leaving group is

Correct order of leaving group tendency is :

Which is the best leaving group ?

CENGAGE CHEMISTRY-ORGANIC REACTION MECHANISM-Comprehension
  1. The leaving group is that functional group which is ejected with overl...

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  2. The leaving group is that functional group which is ejected with overl...

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  3. The leaving group is that functional group which is ejected with overl...

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  4. The leaving group is that functional group which is ejected with overl...

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  5. The leaving group is that functional group which is ejected with overl...

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  6. The leaving group is that functional group which is ejected with overl...

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  7. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  8. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  9. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  10. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  11. Which statement is wrong in the formation of (B) from (A).

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  12. Which is correct in the formation of (c) from (A) ?

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  13. Which statement is wrong in the formation of (c) from (A) ?

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  14. In elimination reaction, the major product is either Saytzeff (more-su...

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  15. In elimination reaction, the major product is either Saytzeff (more-su...

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  16. In elimination reaction, the major product is either Saytzeff (more-su...

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  17. In elimination reaction, the major product is either Saytzeff (more-su...

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  18. In elimination reaction, the major product is either Saytzeff (more-su...

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  19. Consider the following reactions : Which of the following are ste...

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  20. Consider the following reactions : Which of the following regiose...

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