Home
Class 11
CHEMISTRY
Consider the following reactions : I M...

Consider the following reactions :
`I Me- underset((A))(-=)-Me overset(Na+Liq. NH_(3))underset(EtOH)to (B)`
.
Which statement is wrong about the reactions (vii) and (viii) ?

A

The product `(K)` is trans-but-2-ene and product `(L)` is cis-but-2-ene.

B

The product `(K)` is cis-bit-2-ene and product `(L)` is trans-but-2-ene.

C

Anti-elimination of `Br_2` takes place in both the reactions.

D

Both the reactions proceed by `E2` mechanism.

Text Solution

Verified by Experts

The correct Answer is:
B

Both debromination with NaI/acetone or dehydro-halogenation by base proceed by anti-elimination and `E2` machanism.
`{:(,"Reactant",,underset("elimination")("Mechanism of"),"product"),("a".,"Meso or erythro",,"trans (anti)","trans-Alkene"),("b".,(pm)"or threo",,"trans(anti)","cis-Alkene"),("c".,"Meso or erythro",,"cis (syn)","cis- Alkene"),("d".,(pm)"or threo",,"cis(syn)","trans-Alkene"):}`
.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Multiple Correct|30 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Single correct|50 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Subjective|19 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • P-BLOCK GROUP 13 - BORON FAMILY

    CENGAGE CHEMISTRY|Exercise Exercise Archives (Subjecive)|9 Videos

Similar Questions

Explore conceptually related problems

Consider the following reactions : I Me- underset((A))(-=)-Me overset(Na+Liq. NH_(3))underset(EtOH)to (B) . Which statement is wrong about the reactions (i) and (ii) ?

Consider the following reactions : I Me- underset((A))(-=)-Me overset(Na+Liq. NH_(3))underset(EtOH)to (B) . Which statement is wrong about the reactions (iii) and (iv) ?

Consider the following reactions : I Me- underset((A))(-=)-Me overset(Na+Liq. NH_(3))underset(EtOH)to (B) . Which statement is wrong about the reactions (ix) and (x) ?

Consider the following reactions : I Me- underset((A))(-=)-Me overset(Na+Liq. NH_(3))underset(EtOH)to (B) . Which statement is wrong about the reaction (v) and (vi) ?

Products of the following reaction. Me_(2)C-CHCH_(3) overset(i. O_(3))underset(ii.(CH_(3))_(2))Sto ? are

Complete the following reactions: a. Prop-1-"yne"overset(NaNH_2)underset(liq. NH_2)rarr(B)

Consider the following reactions : (I) Me - underset ((A)) -= - Me overset (H_2 +) underset (Pd + BaSO_4) rarr underset ((B)) ? overset (D_2//Pd//C)rarr (C) (II) Me - underset ((A))-= - Me overset (Na + Liq. NH_3) underset (+EtOH)rarr underset ((D)) ? overset (D_2//Pt//C)rarr (E) Which of the following statements are correct ?

Complete the following reactions : (a) (b) ( c) underset((A))(Me-COOH)overset(NH_(2)OH)rarr(B) overset(Theta)overset(OH)rarr(C) (d) ( e) .

CENGAGE CHEMISTRY-ORGANIC REACTION MECHANISM-Comprehension
  1. In elimination reaction, the major product is either Saytzeff (more-su...

    Text Solution

    |

  2. In elimination reaction, the major product is either Saytzeff (more-su...

    Text Solution

    |

  3. Consider the following reactions : Which of the following are ste...

    Text Solution

    |

  4. Consider the following reactions : Which of the following regiose...

    Text Solution

    |

  5. Consider the following reactions : Syn-addition takes place in :

    Text Solution

    |

  6. Consider the following reactions : Anti-addition takes place in :

    Text Solution

    |

  7. Consider the following reactions : Meso-butan-2,3-diol is formed ...

    Text Solution

    |

  8. Consider the following reactions : Racemic-butan-2,3-diol is form...

    Text Solution

    |

  9. Consider the following reactions : The name of structure of MMPP ...

    Text Solution

    |

  10. Consider the following reactions : Which of the following are ste...

    Text Solution

    |

  11. Consider the following reactions : Which of the following regiose...

    Text Solution

    |

  12. Consider the following reactions : Syn-addition takes place in :

    Text Solution

    |

  13. Consider the following reactions : Syn-addition takes place in :

    Text Solution

    |

  14. Meso-tartaric acid is formed in :

    Text Solution

    |

  15. (+-) -Tartaric acid is formed in :

    Text Solution

    |

  16. Consider the following reactions : I Me- underset((A))(-=)-Me overse...

    Text Solution

    |

  17. Consider the following reactions : I Me- underset((A))(-=)-Me overse...

    Text Solution

    |

  18. Consider the following reactions : I Me- underset((A))(-=)-Me overse...

    Text Solution

    |

  19. Consider the following reactions : I Me- underset((A))(-=)-Me overse...

    Text Solution

    |

  20. Consider the following reactions : I Me- underset((A))(-=)-Me overse...

    Text Solution

    |