Home
Class 11
CHEMISTRY
Which of the compound in each of the fol...

Which of the compound in each of the following pairs will react faster in `SN^2` reaction with `overset (Ө) O H`
(A) `MeBr (I) and MeI (II)`
(B) `Me_3 C - Cl (III) and MeCl (IV)`
.

A

`overset ((A)) ((I)) overset ((B)) ((III)) overset ((C))((V))`

B

`overset ((A)) ((I)) overset ((B)) ((IV)) overset ((C))((V))`

C

`overset ((A)) ((II)) overset ((B)) ((III)) overset ((C))((VI))`

D

`overset ((A)) ((II)) overset ((B)) ((IV)) overset ((C))((VI))`

Text Solution

Verified by Experts

The correct Answer is:
D

`(A) (II), I^(Ө)` is a better leaving group than `Br^(Ө)`.
`(B)(V),I^@ RX` undergoes `SN^2` reaction than `3^@ RX`
`(A) (VI)`, Vinyl halide `(V)` does not undergo `SN^1` or `SN^2` reaction , `(VI)` is `1^@ RX`, therefore undergoes `SN^2`.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning|12 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Archives|8 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Multiple Correct|30 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • P-BLOCK GROUP 13 - BORON FAMILY

    CENGAGE CHEMISTRY|Exercise Exercise Archives (Subjecive)|9 Videos

Similar Questions

Explore conceptually related problems

Of the following pairs, which is the faster SN^2 reactions ?

Which compound in each of the following pairs will react faster in S_(N)2 reaction with .^(–)OH ? (i) CH_(3)Br or CH_(3)I , (ii) (CH_(3))_(3)C Cl or CH_(3)Cl

Which compound out of the following pairs will react faster in SN^(1) reaction and why ? CH_(2)=CHBr or CH_(2)=CHCH_2Br

Which compound in each of the following pairs will react faster in S_(N)2 reaction with -OH ? Why? (i) CH_(3)Br or CH_(3)I (ii) (CH_(3))_(3)C Cl or CH_(3)Cl

CENGAGE CHEMISTRY-ORGANIC REACTION MECHANISM-Single correct
  1. Refer to Q.No. 9 above and find out under what condition the reaction ...

    Text Solution

    |

  2. Refer to Q.No. 9 above and find out under what condition the reaction ...

    Text Solution

    |

  3. Which of the compound in each of the following pairs will react faster...

    Text Solution

    |

  4. Which statement is correct about the following reactions ? .

    Text Solution

    |

  5. Which statement is correct about the following reactions ? .

    Text Solution

    |

  6. Which statement is correct about the following reactions ? .

    Text Solution

    |

  7. The decreasing order of dehydrohalogenation of the following compounds...

    Text Solution

    |

  8. The decreasing order of nucleophilicities of the following is : (I) ...

    Text Solution

    |

  9. The decreasing order of nucleophilicities of the following is : (I) ...

    Text Solution

    |

  10. The decreasing order of the basic character of the following is : (I...

    Text Solution

    |

  11. The decreasing order of nucleophilicities in DMSO (dimethylsulphoxide)...

    Text Solution

    |

  12. In which of the following reactions, SN^2 rate increases on changing t...

    Text Solution

    |

  13. In which of the following reactions, retention of configuration takes ...

    Text Solution

    |

  14. Refer to Q.No. 24 and find out in which of the reactions the inversion...

    Text Solution

    |

  15. Refer to Q. No.24 and find out which of the reactions proceeds by SN^i...

    Text Solution

    |

  16. Refer to Q.No. 24 and find out which of the following reactions procee...

    Text Solution

    |

  17. Necessary conditions for Fiels-Alder reactions are :

    Text Solution

    |

  18. Which of the following compounds would undergo Diels-Alder reaction wi...

    Text Solution

    |

  19. Which of the following reaction would undergo Diels-Alder reaction ? ...

    Text Solution

    |

  20. The decresing order of reactivity towards SE (substitution by electrop...

    Text Solution

    |