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Which of the following is the best metho...

Which of the following is the best method for the synthesis of `alpha-`hydroxy butyric acid `(I)` ?
.

A

B

`MeCH = CH_(2) underset("cold")overset(Br_(2) + H_(2)O)(to) underset(H_(2)O^(o+))overset(KCN)(to)`

C

D

Text Solution

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The correct Answer is:
C

(a) is `2^@` halide, so with `C overset Ө C N` elimination can also occur.
(b) would give `beta-`hydroxy butyric acid.

Only `( c)` would give the required product :
( c)
(d) It would give butyric acid (step up by one `C` atom).
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CENGAGE CHEMISTRY-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
  1. The major product ( C) in the reaction is : .

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  2. Which of the following is the best method for the synthesis of ester (...

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  3. Which of the following is the best method for the synthesis of alpha-h...

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  4. Which of the following statements is wrong about the transesterificati...

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  5. The molecular weight of benzoic acid in benzene as determined by depre...

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  6. Which of the following reactions would give a good yield of hydrocarbo...

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  7. Which of the following reactions is not possible ?

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  8. underset((A)) (PhCONH2) underset(KOBr)rarr (B) underset(MeOH)rarr (C) ...

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  9. product (B) is :

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  10. underset((A))(PhCOOH)underset(underset((ii)Ag(2)O //Pt//MeOH)((ii)CH(2...

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  11. Compound (B) is :

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  12. underset((A)) (EtCOOMe) overset("(i)" NH2 NH2 "(ii)" HNO2) underset("(...

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  13. underset((A))("PhCOOMe") overset("(i)" NH2 OH) underset("(ii)" overset...

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  14. Product (B) is :

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  15. Which of the following tests would help in the distinction of HCOOH an...

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  16. Which of the following does not contain (-COOH) group ?

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  17. Acids do not give the characteristic reaction of (C=O) group because o...

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  18. The addition of Hbr to CH2 = CHCOOH results in the formation of.

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  19. Mark the correct order of increasing reactivity.

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  20. CH3COOH overset(Br2//P) rarr (Y) overset((i) KCN) underset((ii) H3 O^...

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