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underset((A)) (PhCONH2) underset(KOBr)ra...

`underset((A)) (PhCONH_2) underset(KOBr)rarr (B) underset(MeOH)rarr (C)`
Product is `( C)` is :

A

`PhNH_2`

B

`PhNHCOOMe`

C

`PhNHCOOPh`

D

None

Text Solution

Verified by Experts

The correct Answer is:
B
Hofmann bromamide reactions. The product `(Ph-N-C=O)` reacts with `MeOH` to give urethane `(Ph-NH-COOMe)`.
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CENGAGE CHEMISTRY-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
  1. Which of the following reactions would give a good yield of hydrocarbo...

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  2. Which of the following reactions is not possible ?

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  3. underset((A)) (PhCONH2) underset(KOBr)rarr (B) underset(MeOH)rarr (C) ...

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  4. product (B) is :

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  5. underset((A))(PhCOOH)underset(underset((ii)Ag(2)O //Pt//MeOH)((ii)CH(2...

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  6. Compound (B) is :

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  7. underset((A)) (EtCOOMe) overset("(i)" NH2 NH2 "(ii)" HNO2) underset("(...

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  8. underset((A))("PhCOOMe") overset("(i)" NH2 OH) underset("(ii)" overset...

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  9. Product (B) is :

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  10. Which of the following tests would help in the distinction of HCOOH an...

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  11. Which of the following does not contain (-COOH) group ?

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  12. Acids do not give the characteristic reaction of (C=O) group because o...

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  13. The addition of Hbr to CH2 = CHCOOH results in the formation of.

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  14. Mark the correct order of increasing reactivity.

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  15. CH3COOH overset(Br2//P) rarr (Y) overset((i) KCN) underset((ii) H3 O^...

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  16. Westrosol overset(90 %H2 SO4)rarr(X) overset(NH3)rarr (Y). Here, Y is ...

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  17. Electrolytic reduction of oxalic acid produces :

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  18. When glycolic acid is subjected to reduction with HI, the product form...

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  19. When lactic acid is subjected to oxidation with Fenton's reagent, the ...

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  20. Which of the following reagents is used for the preparation of citric ...

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