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Mark the correct order of increasing rea...

Mark the correct order of increasing reactivity.

A

`CH_3 CONH_2 lt CH_2 COOC_2 H_5 lt CH_3 COCl`

B

`CH_3 COOC_2 H_5 lt CH_3 COCl lt CH_3 CONH_2`

C

`CH_3 COCl lt CH_3 CONH_2 lt CH_3 COOC_2 H_5`

D

`CH_3 COOC_2H_5 lt CH_3 CONH_2 lt CH_3 COCl`.

Text Solution

Verified by Experts

The correct Answer is:
A

Acyl nucleophilic substitution order is `RCOCl gt ester gt amide`.
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CENGAGE CHEMISTRY-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
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  3. Mark the correct order of increasing reactivity.

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  5. Westrosol overset(90 %H2 SO4)rarr(X) overset(NH3)rarr (Y). Here, Y is ...

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  6. Electrolytic reduction of oxalic acid produces :

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  7. When glycolic acid is subjected to reduction with HI, the product form...

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  8. When lactic acid is subjected to oxidation with Fenton's reagent, the ...

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  10. Treatment of tartaric acid with Fenton's reagent gives :

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  11. A hydrocarbon C6 H12 decolourises bromine solution and yields n-hexane...

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  12. An organic liquid of the composition C4 H8 O2 yields a sodium salt of ...

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  13. On heating calcium acetate and calcium formate, the product formed is ...

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  14. CH3 CH=CHCHO is oxidised to CH3 CH=CHCOOH using :

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  16. Identify Z in the following series CH(2)=CH(2) overset(HBr)rarr X ov...

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  18. Formic acid is obtained when :

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  19. The reaction of HCOOH with conc. H2 SO4 gives :

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  20. The compound which reacts with Fehling's solution is :

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