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Heat is supplied to a diatomic gas at co...

Heat is supplied to a diatomic gas at constant pressure.
The ratio of `DeltaQ : DeltaU : DeltaW` is

A

`5 : 3: 2`

B

`5 : 2: 3`

C

`7 : 5: 2`

D

`7 : 2: 5`

Text Solution

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The correct Answer is:
To solve the problem of finding the ratio of \(\Delta Q : \Delta U : \Delta W\) for a diatomic gas at constant pressure, we can follow these steps: ### Step 1: Understand the relationship between heat, internal energy, and work At constant pressure, the first law of thermodynamics states: \[ \Delta Q = \Delta U + \Delta W \] where: - \(\Delta Q\) is the heat added to the system, - \(\Delta U\) is the change in internal energy, - \(\Delta W\) is the work done by the system. ### Step 2: Calculate \(\Delta Q\) For a diatomic gas at constant pressure, the heat added can be expressed as: \[ \Delta Q = n C_p \Delta T \] where: - \(n\) is the number of moles, - \(C_p\) is the specific heat at constant pressure, - \(\Delta T\) is the change in temperature. For a diatomic gas, \(C_p\) can be derived from the relation: \[ C_p = C_v + R \] where \(C_v\) (specific heat at constant volume) for a diatomic gas is: \[ C_v = \frac{5R}{2} \] Thus, \[ C_p = \frac{5R}{2} + R = \frac{7R}{2} \] Therefore, we can write: \[ \Delta Q = n \left(\frac{7R}{2}\right) \Delta T \] ### Step 3: Calculate \(\Delta U\) The change in internal energy for a diatomic gas is given by: \[ \Delta U = n C_v \Delta T \] Substituting for \(C_v\): \[ \Delta U = n \left(\frac{5R}{2}\right) \Delta T \] ### Step 4: Calculate \(\Delta W\) Using the first law of thermodynamics: \[ \Delta W = \Delta Q - \Delta U \] Substituting the expressions we found for \(\Delta Q\) and \(\Delta U\): \[ \Delta W = n \left(\frac{7R}{2}\right) \Delta T - n \left(\frac{5R}{2}\right) \Delta T \] This simplifies to: \[ \Delta W = n \left(\frac{2R}{2}\right) \Delta T = nR \Delta T \] ### Step 5: Find the ratio \(\Delta Q : \Delta U : \Delta W\) Now we have: - \(\Delta Q = n \left(\frac{7R}{2}\right) \Delta T\) - \(\Delta U = n \left(\frac{5R}{2}\right) \Delta T\) - \(\Delta W = nR \Delta T\) To find the ratio, we can express it as: \[ \Delta Q : \Delta U : \Delta W = \frac{7R}{2} : \frac{5R}{2} : R \] Dividing each term by \(R\) (and factoring out \(n\Delta T\) which is common): \[ = \frac{7}{2} : \frac{5}{2} : 1 \] To eliminate the fractions, we can multiply through by 2: \[ = 7 : 5 : 2 \] ### Final Answer The ratio \(\Delta Q : \Delta U : \Delta W\) is: \[ \boxed{7 : 5 : 2} \]

To solve the problem of finding the ratio of \(\Delta Q : \Delta U : \Delta W\) for a diatomic gas at constant pressure, we can follow these steps: ### Step 1: Understand the relationship between heat, internal energy, and work At constant pressure, the first law of thermodynamics states: \[ \Delta Q = \Delta U + \Delta W \] where: ...
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