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N moles of an ideal diatomic gas are in ...

N moles of an ideal diatomic gas are in a cylinder at temperature T. suppose on supplying heat to the gas, its temperature remain constant but n moles get dissociated into atoms. Heat supplied to the gas is

A

`zero`

B

`(1)/(2) nRT`

C

`(3)/(2) nRT`

D

`(3)/(2)(N - n) RT`

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The correct Answer is:
To solve the problem, we need to understand the dissociation of a diatomic gas into its atomic components and how this affects the heat supplied to the system. ### Step-by-Step Solution: 1. **Understanding the Initial State**: - We have \( N \) moles of a diatomic gas at temperature \( T \). - The internal energy \( U_1 \) of the diatomic gas can be calculated using the formula: \[ U_1 = \frac{f}{2} NRT \] where \( f \) (the degrees of freedom for a diatomic gas) is 5. Thus, \[ U_1 = \frac{5}{2} NRT \] 2. **Dissociation of the Gas**: - When heat is supplied, \( n \) moles of the diatomic gas dissociate into \( n \) moles of monoatomic gas. - After dissociation, the remaining moles of diatomic gas are \( N - n \) and the moles of monoatomic gas are \( n \). 3. **Calculating the Final Internal Energy**: - The internal energy \( U_2 \) after dissociation can be calculated as: \[ U_2 = \text{(Internal energy of remaining diatomic gas)} + \text{(Internal energy of monoatomic gas)} \] - The internal energy of the remaining \( N - n \) moles of diatomic gas is: \[ U_{diatomic} = \frac{5}{2} (N - n) RT \] - The internal energy of \( n \) moles of monoatomic gas is: \[ U_{monoatomic} = \frac{3}{2} n RT \] - Therefore, the total internal energy after dissociation is: \[ U_2 = \frac{5}{2} (N - n) RT + \frac{3}{2} n RT \] 4. **Simplifying the Expression for \( U_2 \)**: - Expanding \( U_2 \): \[ U_2 = \frac{5}{2} NRT - \frac{5}{2} nRT + \frac{3}{2} nRT \] - Combining the terms: \[ U_2 = \frac{5}{2} NRT - \frac{2}{2} nRT = \frac{5}{2} NRT - nRT = \frac{5}{2} NRT - \frac{2}{2} nRT \] 5. **Calculating the Change in Internal Energy**: - The change in internal energy \( \Delta U \) is given by: \[ \Delta U = U_2 - U_1 \] - Substituting the values: \[ \Delta U = \left( \frac{5}{2} NRT - nRT \right) - \frac{5}{2} NRT \] - This simplifies to: \[ \Delta U = -nRT \] 6. **Relating Heat Supplied to Internal Energy**: - Since the temperature is constant, the work done \( W = 0 \) (because \( \Delta V = 0 \)). - Therefore, the heat supplied \( Q \) is equal to the change in internal energy: \[ Q = \Delta U \] - Thus, the heat supplied is: \[ Q = -nRT \] ### Final Answer: The heat supplied to the gas is \( Q = -nRT \).

To solve the problem, we need to understand the dissociation of a diatomic gas into its atomic components and how this affects the heat supplied to the system. ### Step-by-Step Solution: 1. **Understanding the Initial State**: - We have \( N \) moles of a diatomic gas at temperature \( T \). - The internal energy \( U_1 \) of the diatomic gas can be calculated using the formula: \[ ...
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